Specific Intermolecular Interactions of Methoxyamines, Methoxynitriles, and Amides

作者: Alexei K. Baev

DOI: 10.1007/978-3-642-37472-2_6

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摘要: Methoxyamines and ethoxyamines are the simplest hetero compounds with two atoms of oxygen nitrogen. The thermodynamic properties known for a small number these acyclic cyclic compounds; however, one is interested in diversity realized types specific interactions their condensed condition. Shifting electron density at carbon methyl groups leads to an insignificant negative charge [1–3], reducing positive value as result intermolecular reverse dative bond [4–8]

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