Emission Behaviors of Inorganic Ultrafine Particles during Zhundong Coal Oxy-Fuel Combustion with Characterized Oxygen Input Fractions Comparable to Air Combustion

作者: Xin Yu , Bin Fan , Chang Wen , Xianpeng Zeng , Jianqun Wu

DOI: 10.3390/APP8091486

关键词:

摘要: Zhundong low-rank coal is very likely to be utilized extensively in oxy-fired boilers the near future. Its PM10 (particulate matter with an aerodynamic diameter of ≤10 μm) emission behaviors during oxy-fuel combustion need carefully studied before its large-scale use. The present study examines inorganic ultrafine particles (PM0.5, ≤0.5 μm), as well air and conditions (O2/CO2) at three characterized O2 input fractions, i.e., 21, 27 32 vol.%. experiments were carried out a high-temperature drop-tube furnace (HDTF) temperature 1500 °C. results show that PM0.5 composed Na, S, Mg Ca, total fractions ~90%, while PM0.5–10 (with between 0.5 10 predominantly contains Ca (~50–65%). At oxygen (OXY21, 32), promoted fraction was found increase yields both PM0.5–10. A higher particle-burning lower CO2 promote reactions organically bound elements minerals, increasing partitioning causing increased yield PM0.5. from high similar OXY32 OXY27. mainly generated by highest four conditions.

参考文章(48)
C.F. You, X.C. Xu, Coal combustion and its pollution control in China Energy. ,vol. 35, pp. 4467- 4472 ,(2010) , 10.1016/J.ENERGY.2009.04.019
Chang Wen, Xiangpeng Gao, Yun Yu, Jianqun Wu, Minghou Xu, Hongwei Wu, Emission of inorganic PM10 from included mineral matter during the combustion of pulverized coals of various ranks Fuel. ,vol. 140, pp. 526- 530 ,(2015) , 10.1016/J.FUEL.2014.09.114
Chang Wen, Minghou Xu, Ke Zhou, Dunxi Yu, Zhonghua Zhan, Xin Mo, The melting potential of various ash components generated from coal combustion: Indicated by the circularity of individual particles using CCSEM technology Fuel Processing Technology. ,vol. 133, pp. 128- 136 ,(2015) , 10.1016/J.FUPROC.2015.01.012
M. Neville, A.F. Sarofim, The stratified composition of inorganic submicron particles produced during coal combustion Symp. (Int.) Combust., (Proc.); (United States). ,vol. 19, pp. 1441- 1449 ,(1982) , 10.1016/S0082-0784(82)80321-4
Dunxi Yu, Minghou Xu, Hong Yao, Jiancai Sui, Xiaowei Liu, Yun Yu, Qian Cao, Use of elemental size distributions in identifying particle formation modes Proceedings of the Combustion Institute. ,vol. 31, pp. 1921- 1928 ,(2007) , 10.1016/J.PROCI.2006.07.115
Chang Wen, Minghou Xu, Dunxi Yu, Changdong Sheng, Hongwei Wu, Ping’an Zhang, Yu Qiao, Hong Yao, PM10 formation during the combustion of N2-char and CO2-char of Chinese coals Proceedings of the Combustion Institute. ,vol. 34, pp. 2383- 2392 ,(2013) , 10.1016/J.PROCI.2012.07.080
William J. Morris, Dunxi Yu, Jost O.L. Wendt, Soot, unburned carbon and ultrafine particle emissions from air- and oxy-coal flames Proceedings of the Combustion Institute. ,vol. 33, pp. 3415- 3421 ,(2011) , 10.1016/J.PROCI.2010.05.059
Guangqian Luo, Hong Yao, Minghou Xu, Rajenda Gupta, Zhenghe Xu, Identifying modes of occurrence of mercury in coal by temperature programmed pyrolysis Proceedings of the Combustion Institute. ,vol. 33, pp. 2763- 2769 ,(2011) , 10.1016/J.PROCI.2010.06.108
B.J.P. Buhre, L.K. Elliott, C.D. Sheng, R.P. Gupta, T.F. Wall, Oxy-fuel combustion technology for coal-fired power generation Progress in Energy and Combustion Science. ,vol. 31, pp. 283- 307 ,(2005) , 10.1016/J.PECS.2005.07.001