Synthesis of polyarylate through interfacial polycondensation by use of glycolyzed products of poly(ethylene terephthalate) glycolysis with bisphenol-a

作者: Ding-Chang Wang , Chung-Yu Wang , Wen-Yen Chiu , Leo-Wang Chen

DOI: 10.1007/S10965-006-0002-6

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摘要: The glycolysis of poly (ethylene-terephthalate) with bisphenol-A at certain ratios PET/BPA was carried out in an autoclave reactor different temperatures for varying periods time. Then the glycolyzed products were utilized together synthesis polyarylates through interfacial polycondensation. obtained (referred to as b/g-polyarylates this article) possess good thermal characteristics but have lower mechanical strength than typical polyarylate synthesized from pure by use same method. Blending b/g-polyarylate polycarbonate improved impact significantly. As a whole, followed polycondensation provided feasible route reuse poly(ethylene terephthalate).

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