Mercury(II) Cyanide

作者: Pavel Kočovský , Guijun Wang , Vibha Sharma

DOI: 10.1002/047084289X.RM034.PUB2

关键词:

摘要: [592-04-1] C2HgN2 (MW 252.63) InChI = 1S/2CN.Hg/c2*1-2; InChIKey = FQGYCXFLEQVDJQ-UHFFFAOYSA-N (glycosidation reagent1) Alternate Name: mercuric cyanide. Physical Data: mp 320 °C dec; d 3.996 g mL−3. Solubility: insoluble in benzene; soluble H2O, alcohol, NH3; slightly ether. Form Supplied in: colorless, odorless, tetragonal crystals or white powder. Handling, Storage, and Precautions: acute poison. Exposure to all mercury compounds is be strictly avoided. Releases toxic Hg fumes when heated decomposition. Protect from light.

参考文章(40)
Kwan Soo Kim, Jin Hwan Kim, Yong Joo Lee, Yong Jun Lee, Jin Park, 2-(Hydroxycarbonyl)benzyl Glycosides: A Novel Type of Glycosyl Donors for Highly Efficient β-Mannopyranosylation and Oligosaccharide Synthesis by Latent-Active Glycosylation Journal of the American Chemical Society. ,vol. 123, pp. 8477- 8481 ,(2001) , 10.1021/JA015842S
Ge Hyeong Lee, Sung Jin Ha, In Kwon Yoon, Chwang Siek Pak, Intramolecular ketyl-olefin cyclization mediated by magnesium metal Tetrahedron Letters. ,vol. 40, pp. 2581- 2584 ,(1999) , 10.1016/S0040-4039(99)00252-X
Andrew J. Ross, Irina A. Ivanova, Michael A. J. Ferguson, Andrei V. Nikolaev, Parasite glycoconjugates. Part 11. Preparation of phosphodisaccharide synthetic probes, substrate analogues for the elongating α-D-mannopyranosylphosphate transferase in the Leishmania Journal of The Chemical Society-perkin Transactions 1. pp. 72- 81 ,(2001) , 10.1039/B004653L
Dongxu Qiu, Sham S. Gandhi, R.Rao Koganty, βGal(1–3)GalNAc block donor for the synthesis of TF and α Sialy(2–6)TF as glycopeptide building blocks Tetrahedron Letters. ,vol. 37, pp. 595- 598 ,(1996) , 10.1016/0040-4039(95)02229-5
Jie Xia, T. Srikrishnan, James L. Alderfer, R.K. Jain, Conrad F. Piskorz, Khushi L. Matta, Chemical synthesis of sulfated oligosaccharides with a β-d-Gal-(1→3)-[β-d-Gal-(1→4)-(α-l-Fuc-(1→3)-β-d-GlcNAc-(1→6)]-α-d-GalNAc sequence Carbohydrate Research. ,vol. 329, pp. 561- 577 ,(2000) , 10.1016/S0008-6215(00)00211-1
K. C. Nicolaou, Helen J. Mitchell, Nareshkumar F. Jain, Toshikazu Bando, Robert Hughes, Nicolas Winssinger, Swaminathan Natarajan, Alexandros E. Koumbis, Total Synthesis of Vancomycin—Part 4: Attachment of the Sugar Moieties and Completion of the Synthesis Chemistry - A European Journal. ,vol. 5, pp. 2648- 2667 ,(1999) , 10.1002/(SICI)1521-3765(19990903)5:9<2648::AID-CHEM2648>3.0.CO;2-Q
Jens Andersch, Lothar Hennig, Horst Wilde, N-Glycosidation of D-arabino-hex-2-ulosonic acid. Carbohydrate Research. ,vol. 329, pp. 693- 697 ,(2000) , 10.1016/S0008-6215(00)00208-1
Arun K Sarkar, Jillian R Brown, Jeffrey D Esko, Synthesis and glycan priming activity of acetylated disaccharides Carbohydrate Research. ,vol. 329, pp. 287- 300 ,(2000) , 10.1016/S0008-6215(00)00200-7
Yoshitomo Suhara, Yoshiki Yamaguchi, Brian Collins, Ronald L Schnaar, Masaki Yanagishita, James EK Hildreth, Ichio Shimada, Yoshitaka Ichikawa, Oligomers of glycamino acid. Bioorganic & Medicinal Chemistry. ,vol. 10, pp. 1999- 2013 ,(2002) , 10.1016/S0968-0896(02)00020-2