Reactivity of diruthenium and dirhodium analogues of pentaborane(9): agostic versus boratrane complexes.
作者： R. S. Anju , Dipak Kumar Roy , Bijan Mondal , K. Yuvaraj , C. Arivazhagan
关键词:
摘要: A series of novel Cp*-based (Cp*=η5-C5Me5) agostic, bis(σ-borate), and boratrane complexes have been synthesized from diruthenium dirhodium analogues pentaborane(9). The synthesis structural characterization the first neutral ruthenadiborane(6) analogue are also reported. This new route offers a very efficient method for isolation bis(σ-borate) agostic diruthenapentaborane(9).
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