Discrimination of Radix Pseudostellariae according to geographical origins using NIR spectroscopy and support vector data description.

作者: Hao Lin , Jiewen Zhao , Quansheng Chen , Fang Zhou , Li Sun

DOI: 10.1016/J.SAA.2011.04.072

关键词:

摘要: Abstract Near infrared (NIR) spectroscopy combined with support vector data description (SVDD) was attempted to identify geographical origins of Radix Pseudostellariae. Original spectra eggs in wavelength range 10000–4000 cm−1 were acquired. SVDD performed calibrate discrimination model, and some parameters model optimized. Meanwhile, conversional two-class classification method—support machine (SVM) used comparatively for classification. Compared SVM classification, showed its superior ability dealing imbalance training samples. When the proportion number Pseudostellariae from Anhui province (the area where genuine crude cultivated) other provinces one sixteen, identification rate 92.5% prediction set. This work indicates that NIR is an excellent choice building one-class calibration

参考文章(29)
Hao Lin, Quansheng Chen, Jiewen Zhao, Ping Zhou, Determination of free amino acid content in Radix Pseudostellariae using near infrared (NIR) spectroscopy and different multivariate calibrations Journal of Pharmaceutical and Biomedical Analysis. ,vol. 50, pp. 803- 808 ,(2009) , 10.1016/J.JPBA.2009.06.040
David M.J. Tax, Robert P.W. Duin, Support Vector Data Description Machine Learning. ,vol. 54, pp. 45- 66 ,(2004) , 10.1023/B:MACH.0000008084.60811.49
Xiao-Qin Xu, Qing-Ling Li, Ji-Duan Yuan, Shu-Gui Wang, Wen-Shen Wang, Frank S.C. Lee, Xiao-Ru Wang, Determination of three kinds of chloroacetanilide herbicides in radix pseudostellariae by accelerated solvent extraction and gas chromatography-mass spectrometry Chinese Journal of Analytical Chemistry. ,vol. 35, pp. 206- 210 ,(2007) , 10.1016/S1872-2040(07)60036-X
Ondřej Jirsa, Marie Hrušková, Ivan Švec, Near-infrared prediction of milling and baking parameters of wheat varieties Journal of Food Engineering. ,vol. 87, pp. 21- 25 ,(2008) , 10.1016/J.JFOODENG.2007.09.008
Yuna Pan, Jin Chen, Lei Guo, Robust bearing performance degradation assessment method based on improved wavelet packet–support vector data description Mechanical Systems and Signal Processing. ,vol. 23, pp. 669- 681 ,(2009) , 10.1016/J.YMSSP.2008.05.011
Rafael Font, Mercedes del Río-Celestino, Elena Cartea, Antonio de Haro-Bailón, Quantification of glucosinolates in leaves of leaf rape (Brassica napus ssp. pabularia) by near-infrared spectroscopy Phytochemistry. ,vol. 66, pp. 175- 185 ,(2005) , 10.1016/J.PHYTOCHEM.2004.11.011
Olivier Devos, Cyril Ruckebusch, Alexandra Durand, Ludovic Duponchel, Jean-Pierre Huvenne, Support vector machines (SVM) in near infrared (NIR) spectroscopy: Focus on parameters optimization and model interpretation Chemometrics and Intelligent Laboratory Systems. ,vol. 96, pp. 27- 33 ,(2009) , 10.1016/J.CHEMOLAB.2008.11.005