A comparison of pretreatment methods for the analysis of phosphate oxygen isotope ratios in bioapatite
作者： Vaughan Grimes , Maura Pellegrini
DOI: 10.1002/RCM.6463
关键词:
摘要: RATIONALE The integrity of the biological phosphate oxygen isotope (δ18Op) signal is thought to be contingent upon complete removal competing sources such as associated organic matter. A range pretreatment methods purify material from has been reported, with contradictory evidence on usefulness and efficiency one or another. Yet, a systematic comparison these techniques for bioapatite not conducted. METHODS Chemical thermal were tested their effectiveness at removing matter likelihood that they modify original δ18O values. The test was performed in inorganic (synthetic apatite phosphorite rock) (bone tooth tissues) materials which we had an expectation actual δ18Op value. Analysis nitrogen content (wt.%), scanning electron microscopy (SEM) Fourier transform infrared (FTIR) spectroscopy employed. RESULTS We detected variable between no correlation any specific structural change. results showed considerable variation samples pretreated different untreated samples, compositional up 4.5 ‰ bone samples. Variations values within error found enamel, rock apatite. CONCLUSIONS We recommend cautious approach when interpreting comparing data treated protocols. In general, seem show closer expected ones. According our results, completely unnecessary highly mineralized tissues. Copyright © 2012 John Wiley & Sons, Ltd.
mpg.de
sci-hub.se 参考文章(76)
Christine D. White, Michael W. Spence, Fred J. Longstaffe, Kimberley R. Law, Testing the Nature of Teotihuacán Imperialism at Kaminaljuyú Using Phosphate Oxygen-Isotope Ratios Journal of Anthropological Research. ,vol. 56, pp. 535- 558 ,(2000) , 10.1086/JAR.56.4.3630930
Ian D. Clark, Peter Fritz, Environmental Isotopes in Hydrogeology ,(1997)
F. H. Firsching, Precipitation of Silver Phosphate from Homogenous Solution Analytical Chemistry. ,vol. 33, pp. 873- 874 ,(1961) , 10.1021/AC60175A018
Thomas Tütken, Torsten W Vennemann, Hans-Ulrich Pfretzschner, Analyse stabiler und radiogener Isotope in archäologischem Skelettmaterial: Herkunftsbestimmung des karolingischen Maultiers von Frankenthal und Vergleich mit spätpleistozänen Großsäugerknochen aus den Rheinablagerungen Praehistorische Zeitschrift. ,vol. 79, pp. 89- 110 ,(2004) , 10.1515/PRHZ.79.1.89
Ronald A. Crowson, William J. Showers, Ellen K. Wright, Thomas C. Hoering, Preparation of phosphate samples for oxygen isotope analysis Analytical Chemistry. ,vol. 63, pp. 2397- 2400 ,(1991) , 10.1021/AC00020A038
J. Daniel Bryant, Philip N. Froelich, A model of oxygen isotope fractionation in body water of large mammals Geochimica et Cosmochimica Acta. ,vol. 59, pp. 4523- 4537 ,(1995) , 10.1016/0016-7037(95)00250-4
D. D'Angela, A. Longinelli, Oxygen isotopes in living mammal's bone phosphate : further results Chemical Geology: Isotope Geoscience Section. ,vol. 86, pp. 75- 82 ,(1990) , 10.1016/0168-9622(90)90007-Y
Michaela Harbeck, Ramona Schleuder, Julius Schneider, Ingrid Wiechmann, Wolfgang W. Schmahl, Gisela Grupe, Research potential and limitations of trace analyses of cremated remains. Forensic Science International. ,vol. 204, pp. 191- 200 ,(2011) , 10.1016/J.FORSCIINT.2010.06.004
Boaz Luz, Yehoshua Kolodny, Michal Horowitz, Fractionation of oxygen isotopes between mammalian bone-phosphate and environmental drinking water Geochimica et Cosmochimica Acta. ,vol. 48, pp. 1689- 1693 ,(1984) , 10.1016/0016-7037(84)90338-7
Hubert Wierzbowski, Effects of pre-treatments and organic matter on oxygen and carbon isotope analyses of skeletal and inorganic calcium carbonate International Journal of Mass Spectrometry. ,vol. 268, pp. 16- 29 ,(2007) , 10.1016/J.IJMS.2007.08.002