A neutron and X-ray diffraction study of Ca–Mg–Cu metallic glasses

作者: Emma R. Barney , Alex C. Hannon , Oleg N. Senkov , James M. Scott , Daniel B. Miracle

DOI: 10.1016/J.INTERMET.2011.02.001

关键词:

摘要: The structures of Ca60Mg15Cu25, Ca60Mg20Cu20 and Ca60Mg25Cu15 metallic glasses have been investigated by neutron and X-ray diffraction. The correlation functions show a peak manifold in the region 2.2–4.5 Å, arising from the various atom pairs for these glasses. The results show clearly that there are contacts between the solute atoms (Cu and Mg) which agree with a simple estimate of the maximum solute atom fraction beyond which solute–solute contact becomes topologically necessary. The Cu–Mg and Cu–Ca distances …

参考文章(35)
Alan Earnshaw, Norman Neill Greenwood, Chemistry of the elements ,(1984)
Wei-Hua Wang, Qing Wei, S. Friedrich, M. P. Macht, N. Wanderka, H. Wollenberger, Microstructure studies of Zr41Ti14Cu12.5Ni10Be22.5 bulk amorphous alloy by electron diffraction intensity analysis Applied Physics Letters. ,vol. 71, pp. 1053- 1055 ,(1997) , 10.1063/1.119725
Wei-Hua Wang, Q. Wei, S. Friedrich, Microstructure, decomposition, and crystallization in Zr41Ti14Cu12.5Ni10Be22.5 bulk metallic glass Physical Review B. ,vol. 57, pp. 8211- 8217 ,(1998) , 10.1103/PHYSREVB.57.8211
W. KLEMENT, R. H. WILLENS, POL DUWEZ, Non-crystalline Structure in Solidified Gold–Silicon Alloys Nature. ,vol. 187, pp. 869- 870 ,(1960) , 10.1038/187869B0
Wei-Hua Wang, Chuang Dong, CH Shek, Bulk metallic glasses Materials Science & Engineering R-reports. ,vol. 44, pp. 45- 89 ,(2004) , 10.1016/J.MSER.2004.03.001
P. G. Mikolaj, C. J. Pings, The Use of the Coordination Number in the Interpretation of Fluid Structure Physics and Chemistry of Liquids. ,vol. 1, pp. 93- 108 ,(1968) , 10.1080/00319106808083789
O. N. Senkov, D. B. Miracle, E. R. Barney, A. C. Hannon, Y. Q. Cheng, E. Ma, Local atomic structure of Ca-Mg-Zn metallic glasses Physical Review B. ,vol. 82, pp. 104206- ,(2010) , 10.1103/PHYSREVB.82.104206
O.N. Senkov, J.M. Scott, Glass forming ability and thermal stability of ternary Ca-Mg-Zn bulk metallic glasses Journal of Non-crystalline Solids. ,vol. 351, pp. 3087- 3094 ,(2005) , 10.1016/J.JNONCRYSOL.2005.07.022
O.N. Senkov, J.M. Scott, D.B. Miracle, Composition range and glass forming ability of ternary Ca–Mg–Cu bulk metallic glasses Journal of Alloys and Compounds. ,vol. 424, pp. 394- 399 ,(2006) , 10.1016/J.JALLCOM.2006.01.104
Junji Saida, Muneyuki Imafuku, Shigeo Sato, Takashi Sanada, Eiichiro Matsubara, Akihisa Inoue, Correlation between local structure and stability of supercooled liquid state in Zr-based metallic glasses Materials Science and Engineering: A. ,vol. 449-451, pp. 90- 94 ,(2007) , 10.1016/J.MSEA.2006.02.334