Electrospinning synthesis and luminescent properties of one-dimensional Ca2Gd8(SiO4)6O2:Eu3+ microfibers and microbelts

作者: Chong Peng , Guogang Li , Zhiyao Hou , Mengmeng Shang , Jun Lin

DOI: 10.1016/J.MATCHEMPHYS.2012.08.040

关键词:

摘要: One-dimensional Ca2Gd8(SiO4)(6)O-2:Eu3+ microfibers and microbelts were fabricated by a simple cost-effective electrospinning method. X-ray diffraction (XRD). Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), transmission (TEM), high-resolution (HRTEM), photoluminescence (PL), cathodoluminescence (CL) decay kinetics used to characterize the resulting samples. The diameters of annealed at 1000 degrees C in range 130-210 nm. width thickness 290-500 nm 110-160 nm, respectively. When samples excited ultraviolet (275 nm), intense red emission from Eu3+ ions was observed. charge transfer band broader than peak moved lower energy area. Under low-voltage beams (3-5 kV) excitation, also showed strong emission. (C) 2012 Elsevier B.V. All rights reserved.

参考文章(52)
Yuexiao Pan, Qiang Su, Huifang Xu, Tianhu Chen, Weikun Ge, Chunlei Yang, Mingmei Wu, Synthesis and red luminescence of Pr3+-doped CaTiO3 nanophosphor from polymer precursor Journal of Solid State Chemistry. ,vol. 174, pp. 69- 73 ,(2003) , 10.1016/S0022-4596(03)00175-0
G. Seeta Rama Raju, Jin Young Park, Hong Chae Jung, Byung Kee Moon, Jung Hyun Jeong, Jung Hwan Kim, Gd3 + Sensitization Effect on the Luminescence Properties of Tb3 + Activated Calcium Gadolinium Oxyapatite Nanophosphors Journal of The Electrochemical Society. ,vol. 158, ,(2011) , 10.1149/1.3511786
Yi-Chen Chiu, Wei-Ren Liu, Chun-Kuei Chang, Cheng-Chun Liao, Yao-Tsung Yeh, Shyue-Ming Jang, Teng-Ming Chen, Ca2PO4Cl:Eu2+: an intense near-ultraviolet converting blue phosphor for white light-emitting diodes Journal of Materials Chemistry. ,vol. 20, pp. 1755- 1758 ,(2010) , 10.1039/B920610H
N. Hirosaki, R.-J. Xie, K. Inoue, T. Sekiguchi, B. Dierre, K. Tamura, Blue-emitting AlN:Eu2+ nitride phosphor for field emission displays Applied Physics Letters. ,vol. 91, pp. 061101- ,(2007) , 10.1063/1.2767182
Hui Wu, Yao Sun, Dandan Lin, Rui Zhang, Chen Zhang, Wei Pan, GaN Nanofibers based on Electrospinning: Facile Synthesis, Controlled Assembly, Precise Doping, and Application as High Performance UV Photodetector Advanced Materials. ,vol. 21, pp. 227- 231 ,(2009) , 10.1002/ADMA.200800529
K. Vivekanandan, S. Selvasekarapandian, P. Kolandaivel, Raman and FT-IR studies of Pb4(NO3)2(PO4)2·2H2O crystal Materials Chemistry and Physics. ,vol. 39, pp. 284- 289 ,(1995) , 10.1016/0254-0584(94)01440-R
Jun Lin, Qiang Su, Luminescence of Pb2+ and energy transfer from Pb2+ to rare earth ions in silicate oxyapatites Physica Status Solidi B-basic Solid State Physics. ,vol. 196, pp. 261- 267 ,(1996) , 10.1002/PSSB.2221960126
Ling Li, Hyun Kyoung Yang, Byung Kee Moon, Byung Chun Choi, Jung Hyun Jeong, Kwang Ho Kim, Photoluminescent properties of Ln2O3:Eu3+ (Ln=Y, Lu and Gd) prepared by hydrothermal process and sol–gel method Materials Chemistry and Physics. ,vol. 119, pp. 471- 477 ,(2010) , 10.1016/J.MATCHEMPHYS.2009.09.027
Guoping Dong, Xiudi Xiao, Liaolin Zhang, Zhijun Ma, Xin Bao, Mingying Peng, Qinyuan Zhang, Jianrong Qiu, Preparation and optical properties of red, green and blue afterglow electrospun nanofibers Journal of Materials Chemistry. ,vol. 21, pp. 2194- 2203 ,(2011) , 10.1039/C0JM02851G
Andreas Greiner, Joachim H. Wendorff, Electrospinning: A Fascinating Method for the Preparation of Ultrathin Fibers Angewandte Chemie. ,vol. 46, pp. 5670- 5703 ,(2007) , 10.1002/ANIE.200604646