Hydrogen Evolution Catalyzed by Cu2WS4 at Liquid–Liquid Interfaces

作者: Faruk Ozel , Emre Aslan , Adem Sarilmaz , Imren Hatay Patir

DOI: 10.1021/ACSAMI.6B05582

关键词:

摘要: The present study reports, for the first time, both a facile synthesis for ternary Cu2WS4 nanocubes, which were synthesized by a simple and low-cost hot-injection method, and the hydrogen evolution reaction at a biomembrane-like polarized water/1, 2-dichloroethane interface catalyzed by Cu2WS4 nanocubes. The rate of hydrogen evolution reaction is increased by about 1000 times by using Cu2WS4 nanocubes when compared to an uncatalyzed reaction.

参考文章(37)
Huan Pang, Yi-Zhou Zhang, Zhen Run, Wen-Yong Lai, Wei Huang, Amorphous nickel pyrophosphate microstructures for high-performance flexible solid-state electrochemical energy storage devices Nano Energy. ,vol. 17, pp. 339- 347 ,(2015) , 10.1016/J.NANOEN.2015.07.030
T. F. Jaramillo, K. P. Jorgensen, J. Bonde, J. H. Nielsen, S. Horch, I. Chorkendorff, Identification of active edge sites for electrochemical H2 evolution from MoS2 nanocatalysts. Science. ,vol. 317, pp. 100- 102 ,(2007) , 10.1126/SCIENCE.1141483
Jacob Bonde, Poul G. Moses, Thomas F. Jaramillo, Jens K. Nørskov, Ib Chorkendorff, Hydrogen evolution on nano-particulate transition metal sulfides. Faraday Discussions. ,vol. 140, pp. 219- 231 ,(2009) , 10.1039/B803857K
Imren Hatay, Pei Yu Ge, Heron Vrubel, Xile Hu, Hubert H. Girault, Hydrogen evolution at polarised liquid/liquid interfaces catalyzed by molybdenum disulfide Energy and Environmental Science. ,vol. 4, pp. 4246- 4251 ,(2011) , 10.1039/C1EE01996A
Phong D. Tran, Sing Yang Chiam, Pablo P. Boix, Yi Ren, Stevin S. Pramana, Jennifer Fize, Vincent Artero, James Barber, Novel cobalt/nickel–tungsten-sulfide catalysts for electrocatalytic hydrogen generation from water Energy and Environmental Science. ,vol. 6, pp. 2452- 2459 ,(2013) , 10.1039/C3EE40600H
Tanyuan Wang, Lu Liu, Zhiwei Zhu, Pagona Papakonstantinou, Jingbo Hu, Hongyun Liu, Meixian Li, Enhanced electrocatalytic activity for hydrogen evolution reaction from self-assembled monodispersed molybdenum sulfide nanoparticles on an Au electrode Energy and Environmental Science. ,vol. 6, pp. 625- 633 ,(2013) , 10.1039/C2EE23513G
Anders B. Laursen, Søren Kegnæs, Søren Dahl, Ib Chorkendorff, Molybdenum sulfides—efficient and viable materials for electro - and photoelectrocatalytic hydrogen evolution Energy and Environmental Science. ,vol. 5, pp. 5577- 5591 ,(2012) , 10.1039/C2EE02618J
Mahmut Kus, Faruk Ozel, Sumeyra Buyukcelebi, Abdalaziz Aljabour, Aysenur Erdogan, Mustafa Ersoz, Niyazi Serdar Sariciftci, Colloidal CuZnSnSe4−xSx nanocrystals for hybrid solar cells Optical Materials. ,vol. 39, pp. 103- 109 ,(2015) , 10.1016/J.OPTMAT.2014.11.007
Wenxing Chen, Haiping Chen, Hangtian Zhu, Qingqing Gao, Jun Luo, Yu Wang, Shuo Zhang, Ke Zhang, Chengming Wang, Yujie Xiong, Yanfei Wu, Xusheng Zheng, Wangsheng Chu, Li Song, Ziyu Wu, Solvothermal Synthesis of Ternary Cu2MoS4Nanosheets: Structural Characterization at the Atomic Level Small. ,vol. 10, pp. 4637- 4644 ,(2014) , 10.1002/SMLL.201400752