SO2 Gas Physicochemical Removal through Pulse Streamer Discharge Technique Assisted by Vapor Additive

作者: Xiaojun Wang , Lianshui Zhang

DOI: 10.1155/2015/872964

关键词:

摘要: SO2 removal has drawn extensive attentions for air pollution treatment. In this paper, the pulse streamer discharge technique is investigated. Emission spectra diagnosis experimentally indicates that molecule been physically dissociated into SO and O radicals by electron collision can be remediated through further chemical reactions during after discharge. order to quantitatively analyze physical chemistry kinetics, a zero-dimensional physicochemical reaction model established. Without H2O vapor additive, efficiency leanly low only 0.296% achieved under duration of 0.5 μs. Through increasing electrical concentration six times, slightly heightened 1.796% at 3 μs. Contrarily, additive effectively improve remarkably 13.0195% 0.5 μs with H2O/SO2 initial ratio 0.1 : 1. OH decomposed from are essential factor achieve such improvement, which have adjusted process favorite directions. The major productions transformed HSO3 HOSO2 H2SO4 when increased above 1.27 : 1.

参考文章(45)
M. Tsuji, H. Fukutome, K. Tsuji, Y. Nishimura, SO2+(C̃−X̃) fluorescence from Penning ionization of SO2 International Journal of Mass Spectrometry and Ion Physics. ,vol. 28, pp. 257- 265 ,(1978) , 10.1016/0020-7381(78)80090-4
Junji Cao, Xuexi Tie, Walter F. Dabberdt, Tang Jie, Zhuzi Zhao, Zhisheng An, Zhenxing Shen, Yinchang Feng, On the potential high acid deposition in northeastern China Journal of Geophysical Research. ,vol. 118, pp. 4834- 4846 ,(2013) , 10.1002/JGRD.50381
Jacinth Naidoo, A. Goumri, Paul Marshall, A kinetic study of the reaction of atomic oxygen with SO2 Proceedings of the Combustion Institute. ,vol. 30, pp. 1219- 1225 ,(2005) , 10.1016/J.PROCI.2004.08.214
Hongbin Ma, Paul Chen, Minglang Zhang, Xiangyang Lin, Roger Ruan, Study of SO2 Removal Using Non-thermal Plasma Induced by Dielectric Barrier Discharge (DBD) Plasma Chemistry and Plasma Processing. ,vol. 22, pp. 239- 284 ,(2002) , 10.1023/A:1014895409454
Michael A. A. Clyne, Paul H. Tennyson, A 3 Π and B3Σ– excited states of the SO radical. Part 3.—The 0–0 band spectrum of the A3Π1–X3Σ– transition Journal of the Chemical Society, Faraday Transactions. ,vol. 82, pp. 1315- 1325 ,(1986) , 10.1039/F29868201315
D. L. Singleton, R. J. Cvetanović, Evaluated Chemical Kinetic Data for the Reactions of Atomic Oxygen O(3P) with Sulfur Containing Compounds Journal of Physical and Chemical Reference Data. ,vol. 17, pp. 1377- 1437 ,(1988) , 10.1063/1.555811
Dong-Lan Wu, An-Dong Xie, Xiao-Guang Yu, Hui-Jun Wan, The analytical potential energy function of flue gas SO2(X1A1) Chinese Physics B. ,vol. 21, pp. 043103- ,(2012) , 10.1088/1674-1056/21/4/043103
Vivekanand Gaur, Ritesh Asthana, Nishith Verma, Removal of SO2 by activated carbon fibers in the presence of O2 and H2O Carbon. ,vol. 44, pp. 46- 60 ,(2006) , 10.1016/J.CARBON.2005.07.012