Synthesis of 2-ethyl-2-hexenal oxime and its flotation performance for copper ore
作者： Haifeng Xu , Hong Zhong , Shuai Wang , Yanan Niu , Guangyi Liu
DOI: 10.1016/J.MINENG.2014.06.011
关键词:
摘要: Abstract A novel collector 2-ethyl-2-hexenal oxime was synthesized from and hydroxylamine hydrochloride. The yield of 78.05% under the optimum experimental conditions. characterized by elemental analysis, infrared spectrum, mass 1 H NMR 13 C spectroscopy. results ultraviolet spectrum showed that exhibited stronger reaction affinity with Cu 2+ than Ni or Fe 3+ , etc. Infrared spectroscopic analysis implicated bound to through both N groups. Microflotation tests pure malachite mineral chalcopyrite indicated recovery 91.16% flotation condition rougher pH 10 concentration 200 mg/L, reached 90.56% 11.5 250 mg/L. sulfide–oxide copper Dexing mine achieved an excellent mean containing 4.52% 79.54% recovery, average increased 2.35% compared butyl xanthate.
sci-hub.se 参考文章(20)
R.G. Shotter, D. Sesardić, P.H. Wright, α,β-unsaturated oximes Tetrahedron. ,vol. 31, pp. 3069- 3072 ,(1975) , 10.1016/0040-4020(75)80149-9
Louis Frederick Fieser, Experiments in organic chemistry ,(1935)
Raymond Eller Kirk, Donald Frederick Othmer, Encyclopedia of Chemical Technology ,(1998)
Sosale Chandrasekhar, Kovuru Gopalaiah, Beckmann rearrangement in the solid state: reaction of oxime hydrochlorides Tetrahedron Letters. ,vol. 42, pp. 8123- 8125 ,(2001) , 10.1016/S0040-4039(01)01737-3
Naveen Anand, Nathan A. Owston, Alexandra J. Parker, Paul A. Slatford, Jonathan M.J. Williams, Ruthenium-catalysed conversion of oxime ethers into nitriles Tetrahedron Letters. ,vol. 48, pp. 7761- 7763 ,(2007) , 10.1016/J.TETLET.2007.09.028
Antti Pohjakallio, Petri M. Pihko, Enantioselective Synthesis of 2-Isoxazolines by a One-Flask Conjugate Addition/Oxime-Transfer Process Chemistry: A European Journal. ,vol. 15, pp. 3960- 3964 ,(2009) , 10.1002/CHEM.200802684
Kanniyappan Parthasarathy, Chien-Hong Cheng, Easy Access to Isoquinolines and Tetrahydroquinolines from Ketoximes and Alkynes via Rhodium-Catalyzed C−H Bond Activation Journal of Organic Chemistry. ,vol. 74, pp. 9359- 9364 ,(2009) , 10.1021/JO902084J
Archana Agrawal, M.K. Manoj, S. Kumari, D. Bagchi, V. Kumar, B.D. Pandey, Extractive separation of copper and nickel from copper bleed stream by solvent extraction route Minerals Engineering. ,vol. 21, pp. 1126- 1130 ,(2008) , 10.1016/J.MINENG.2008.02.016
Padma Desaraju, Anthony Winston, SYNTHESIS AND IRON COMPLEXATION STUDIES OF BIS-HYDROXAMIC ACIDS Journal of Coordination Chemistry. ,vol. 14, pp. 241- 248 ,(1986) , 10.1080/00958978608073914
D.W Fuerstenau, R Herrera-Urbina, D.W McGlashan, Studies on the applicability of chelating agents as universal collectors for copper minerals International Journal of Mineral Processing. ,vol. 58, pp. 15- 33 ,(2000) , 10.1016/S0301-7516(99)00058-7