Photochemistry of Transition Metal Complexes
作者： Tom Bitterwolf
DOI: 10.1002/9781119951438.EIBC0174
关键词:
摘要: Photochemistry has evolved into a powerful tool for the highly selective generation of reactive intermediates in inorganic and organometallic chemistry. This review examines state art examination mechanisms photochemical reactions utilizing techniques such as frozen matrices fast time-resolved methods. The application photochemistry to preparation dihydrogen, alkane, noble gas is reviewed along with significance these understanding mechanism oxidative addition processes. Experiment theory charge transfer phenomena are extensively discussed processes semiconductor biochemical studies. Applications photocrystallography linkage isomers very short-lived excited species reviewed. Finally, number examples reactions, photolysis Fisher carbene generate ketenelike intermediates, synthesis discussed. literature end 2003. Keywords: organometallic photochemistry; inorganic photochemistry; metal ligand transfer; metal–metal bond homolysis; radical reactions; bond heterolysis; linkage isomerism; photochemical loss; dihydrogen complexes; agostic interactions; alkane complexes; noble complexes; photochemical cycloaddition; metal-mediated cycloaddition; photochemical Pauson–Khand reaction; photochemical catalysis initiation; CH activation; CH addition; cyclometallation; SiH activation; SiH addition; photochemical intermediates; matrix-isolation photochemistry; inert matrices; liquid inert solvent photochemistry; supercritical photochemistry; time-resolved spectroscopy; picosecond spectroscopy; dft modeling states; electrospray photochemistry; charge DNA applications; DNA electron transport; protein transport; charge semiconductors; gas-phase photochemistry; Fisher photochemistry; photochemical synthetic applications; femtosecond carbonyl nitrosyl diimine photochemistry; diimine photochemistry; photoacoustic calorimetry; photochemical flow reactor; photochemical borylation; photochemical carbonylation; photochemistry bimetallic compounds; photocrystallography; photopharmaceutical applications; Roussin's salts; Roussin's esters
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