New ionic fluorenylnickel complexes: Synthesis and solid state structure
作者： Andrzej Kozioł , Lucjan B. Jerzykiewicz , Iwona Justyniak , Tadeusz Lis , Stanisław Pasynkiewicz
DOI: 10.1016/J.JORGANCHEM.2014.05.026
关键词:
摘要: Abstract New fluorenylnickel complexes [M(THF)n]+[Ni(η5-Flu)(η1-Flu)2]− (M = +48 Li, 1 and M = Na, 2) have been obtained in the reaction of nickel bromide with fluorenyllithium -sodium. The X-ray molecular structures (monoclinic; P21/c) 2 (orthorhombic; Fdd2) reveal that both two fluorenyl ligands are bonded to atom by η1 bond third one is η5 bond. Complexes first structurally characterized bearing ligands.
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