Selective hydrogenation of 3,3-dimethylbutanoyl chloride to 3,3-dimethylbutyraldehyde with silica supported Pd nanoparticle catalyst
作者： Sifang Li , Guoqin Chen , Lan Sun
DOI: 10.1016/J.CATCOM.2011.01.025
关键词:
摘要: Abstract A novel method for selective hydrogenation of 3,3-dimethylbutanoyl chloride (DMBC) to 3,3-dimethylbutyraldehyde (DMBA) with silica supported Pd nanoparticle catalyst (Pd/SiO2) is developed. The catalysts were characterized by Fourier transform infrared spectroscopy, X-ray powder diffraction, N2 physisorption and transmission electron microscopy. performance the Pd/SiO2 was compared Pd/C Pd/BaSO4 or without being pretreated quinoline–sulfur. activated at 80 °C bubbling hydrogen in cyclohexane 1 h showed highest yield DMBA. For 3 wt.% Pd/SiO2, DMBA reached 84.6%, which exhibited much higher value than catalysts.
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R. Linacero, M. L. Rojas-Cervantes, J. De D. López-González, Influence of the synthesis methods on the physical and structural characteristics of 0.6TiO2·0.4Al2O3 catalytic supports Journal of Materials Science. ,vol. 35, pp. 3269- 3278 ,(2000) , 10.1023/A:1004875322935
Antony J. Hannaford, Peter W. G. Smith, Austin R. Tatchell, Brian S. Furniss, Vogel's Textbook of Practical Organic Chemistry ,(1996)
S. Affrossman, S. J. Thomson, 378. Selective poisoning of the catalyst in the Rosenmund reaction Journal of the Chemical Society (Resumed). pp. 2024- 2029 ,(1962) , 10.1039/JR9620002024
A QUINTANILLA, J BAKKER, M KREUTZER, J MOULIJN, F KAPTEIJN, Tuning the support adsorption properties of Pd/SiO2 by silylation to improve the selective hydrogenation of aromatic ketones Journal of Catalysis. ,vol. 257, pp. 55- 63 ,(2008) , 10.1016/J.JCAT.2008.04.006
Vasanti G. Yadav, S. B. Chandalia, Synthesis of Aldehydes by Rosenmund Reduction Organic Process Research & Development. ,vol. 1, pp. 226- 232 ,(1997) , 10.1021/OP960024J
S. Tanaka, F. Mizukami, S. Niwa, M. Toba, Gy. Tasi, K. Kunimori, Highly selective formation of aldehydes in the hydrogenation of the corresponding acid chlorides with silica-supported palladium catalysts prepared by a complexing agent-assisted sol–gel method Applied Catalysis A-general. ,vol. 229, pp. 175- 180 ,(2002) , 10.1016/S0926-860X(02)00026-1
Jan Pospíšek, Karel Bláha, PEPTIDES CONTAINING A NEOPENTYLGLYCINE RESIDUE Collection of Czechoslovak Chemical Communications. ,vol. 52, pp. 514- 521 ,(1987) , 10.1135/CCCC19870514
Albert W. BURGSTAHLER, Leland O. WEIGEL, Craig G. SHAEFER, Improved Modification of the Rosenmund Reduction Synthesis. ,vol. 1976, pp. 767- 768 ,(1976) , 10.1055/S-1976-24198
Joongjai Panpranot, Kanda Pattamakomsan, James G. Goodwin, Piyasan Praserthdam, A comparative study of Pd/SiO2 and Pd/MCM-41 catalysts in liquid-phase hydrogenation Catalysis Communications. ,vol. 5, pp. 583- 590 ,(2004) , 10.1016/J.CATCOM.2004.07.008
CM Liu, XT Zu, QM Wei, LM Wang, None, Fabrication and characterization of wire-like SnO2 Journal of Physics D. ,vol. 39, pp. 2494- 2497 ,(2006) , 10.1088/0022-3727/39/12/004