DEGRADATION OF POLY(3-HYDROXYBUTYRATE) AND ITS DERIVATIVES: CHARACTERIZATION AND KINETIC BEHAVIOR
作者： , , , ,
关键词:
摘要: We focused on hydrolytic degradation kinetics at 310 and 343 K in phosphate buffer to compare PLA PHB kinetic profiles. Besides, we revealed the behavior for copolymer PHBV (20 % of 3-hydroxyvalerate) blend PHB-PLA (1:1). The intensity biopolymer hydrolysis is characterized by total weight lost viscosity-averaged molecular (MW) decrement. enhanced series < PLA. Characterization includes MW crystallinity evolution (X-ray diffraction) as well AFM analysis film surfaces before after aggressive medium exposition. important impact shown.
sci-hub.st 参考文章(27)
Yoshiharu Doi, Youko Kanesawa, Yasushi Kawaguchi, Masao Kunioka, Hydrolytic degradation of microbial poly(hydroxyalkanoates) Die Makromolekulare Chemie, Rapid Communications. ,vol. 10, pp. 227- 230 ,(1989) , 10.1002/MARC.1989.030100506
L.J.R. Foster, V. Sanguanchaipaiwong, C.L. Gabelish, J. Hook, M. Stenzel, A natural-synthetic hybrid copolymer of polyhydroxyoctanoate-diethylene glycol: biosynthesis and properties Polymer. ,vol. 46, pp. 6587- 6594 ,(2005) , 10.1016/J.POLYMER.2005.05.012
Yuan Gao, Lijun Kong, Ling Zhang, Yandao Gong, Guoqiang Chen, Nanming Zhao, Xiufang Zhang, None, Improvement of mechanical properties of poly(DL-lactide) films by blending of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) European Polymer Journal. ,vol. 42, pp. 764- 775 ,(2006) , 10.1016/J.EURPOLYMJ.2005.09.028
W. D. Luzier, Materials derived from biomass/biodegradable materials. Proceedings of the National Academy of Sciences of the United States of America. ,vol. 89, pp. 839- 842 ,(1992) , 10.1073/PNAS.89.3.839
Yves Marois, Ze Zhang, Michel Vert, Xiaoyan Deng, Robert Lenz, Robert Guidoin, Mechanism and rate of degradation of polyhydroxyoctanoate films in aqueous media: A long-term in vitro study. Journal of Biomedical Materials Research. ,vol. 49, pp. 216- 224 ,(2000) , 10.1002/(SICI)1097-4636(200002)49:2<216::AID-JBM9>3.0.CO;2-X
N.D. Miller, D.F. Williams, On the biodegradation of poly-β-hydroxybutyrate (PHB) homopolymer and poly-β-hydroxybutyrate-hydroxyvalerate copolymers Biomaterials. ,vol. 8, pp. 129- 137 ,(1987) , 10.1016/0142-9612(87)90102-5
Thomas Freier, Carmen Kunze, Claudia Nischan, Sven Kramer, Katrin Sternberg, Marko Saß, Ullrich T. Hopt, Klaus-Peter Schmitz, In vitro and in vivo degradation studies for development of a biodegradable patch based on poly(3-hydroxybutyrate). Biomaterials. ,vol. 23, pp. 2649- 2657 ,(2002) , 10.1016/S0142-9612(01)00405-7
HT Wang, H Palmer, Robert J Linhardt, Dr R Flanagan, E Schmitt, Degradation of poly(ester) microspheres. Biomaterials. ,vol. 11, pp. 679- 685 ,(1990) , 10.1016/0142-9612(90)90026-M
K Molnár, J Moczo, Marius Murariu, Philippe Dubois, B Pukánszky, None, Factors affecting the properties of PLA/CaSO4 composites: homogeneity and interactions Express Polymer Letters. ,vol. 3, pp. 49- 61 ,(2009) , 10.3144/EXPRESSPOLYMLETT.2009.8
X QU, Q WU, K ZHANG, G CHEN, In vivo studies of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) based polymers: Biodegradation and tissue reactions Biomaterials. ,vol. 27, pp. 3540- 3548 ,(2006) , 10.1016/J.BIOMATERIALS.2006.02.015