Green Electrochemical Synthesis of N-Phenylquinoneimine Derivatives: Dual Action of 4-Morpholinoaniline and N-(4-Aminophenyl) Acetamide
作者： Mahdi Jamshidi , Davood Nematollahi
DOI: 10.1021/ACSSUSCHEMENG.7B02553
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摘要: In this paper, two green electrochemical strategies for the synthesis of new N-phenylquinoneimine derivatives are reported. first strategy, electrophilic activity electrochemically generated quinone–diimine was used in reaction with phenol as a model nucleophile. second formed 4-tert-butyl-o-benzoquinone Michael acceptor 4-morpholinoaniline, N-(4-aminophenyl) acetamide, and fast violet B. The mechanism both is electron transfer−chemical reaction−electron transfer/disproportionation (ECE/DISP). This study provided some good yields by one-pot under ambient conditions without toxic reagents.
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