Carbon and Nitrogen Co-doped TiO2 with Enhanced Visible-Light Photocatalytic Activity

作者: Daimei Chen , Zhongyi Jiang , Jiaqing Geng , Qun Wang , Dong Yang

DOI: 10.1021/IE061491K

关键词:

摘要: To utilize visible light more efficiently in photocatalytic reactions, carbon-doped TiO2 (C−TiO2), nitrogen-doped (N−TiO2), and carbon nitrogen co-doped (C−N−TiO2) nanoparticles with different contents were prepared by a sol−gel method characterized X-ray diffraction (XRD), transmission electron microscopy (TEM), photoelectron spectroscopy (XPS), UV−vis spectroscopy. XRD results showed that the doping of C N atoms could suppress crystal growth TiO2, effect was pronounced than doping. XPS, spectroscopy, lattice parameter analysis revealed incorporate into anatase through substituting sites oxygen atoms, while most form mixed layer deposited active complex carbonate species at surface nanoparticles. The activities obtained C−TiO2, N−TiO2, C−N−TiO2 samples evalua...

参考文章(36)
Xiaobo Chen, Yongbing Lou, Anna C. Samia, Clemens Burda, Coherency Strain Effects on the Optical Response of Core/Shell Heteronanostructures Nano Letters. ,vol. 3, pp. 799- 803 ,(2003) , 10.1021/NL034243B
Takashi Tachikawa, Sachiko Tojo, Kiyohiko Kawai, Masayuki Endo, Mamoru Fujitsuka, Teruhisa Ohno, Kazumoto Nishijima, Zenta Miyamoto, Tetsuro Majima, Photocatalytic Oxidation Reactivity of Holes in the Sulfur- and Carbon-Doped TiO2 Powders Studied by Time-Resolved Diffuse Reflectance Spectroscopy Journal of Physical Chemistry B. ,vol. 108, pp. 19299- 19306 ,(2004) , 10.1021/JP0470593
Akihiko Hattori, Koji Shimoda, Hiroaki Tada, Seishiro Ito, Photoreactivity of Sol−Gel TiO2 Films Formed on Soda-Lime Glass Substrates: Effect of SiO2 Underlayer Containing Fluorine Langmuir. ,vol. 15, pp. 5422- 5425 ,(1999) , 10.1021/LA981148N
Eugène Papirer, Renaud Lacroix, Jean-Baptiste Donnet, Gérard Nansé, Philippe Fioux, XPS study of the halogenation of carbon black—Part 2. Chlorination Carbon. ,vol. 33, pp. 1341- 1358 ,(1994) , 10.1016/0008-6223(94)00111-C
Torbjörn Lindgren, Julius M. Mwabora, Esteban Avendaño, Jacob Jonsson, Anders Hoel, Claes-Göran Granqvist, Sten-Eric Lindquist, Photoelectrochemical and Optical Properties of Nitrogen Doped Titanium Dioxide Films Prepared by Reactive DC Magnetron Sputtering Journal of Physical Chemistry B. ,vol. 107, pp. 5709- 5716 ,(2003) , 10.1021/JP027345J
Andreas Kay, Robin Humphry-Baker, Michael Graetzel, Artificial Photosynthesis. 2. Investigations on the Mechanism of Photosensitization of Nanocrystalline TiO2 Solar Cells by Chlorophyll Derivatives The Journal of Physical Chemistry. ,vol. 98, pp. 952- 959 ,(1994) , 10.1021/J100054A035
Isao Nakamura, Nobuaki Negishi, Shuzo Kutsuna, Tatsuhiko Ihara, Shinichi Sugihara, Koji Takeuchi, Role of oxygen vacancy in the plasma-treated TiO2 photocatalyst with visible light activity for NO removal Journal of Molecular Catalysis A-chemical. ,vol. 161, pp. 205- 212 ,(2000) , 10.1016/S1381-1169(00)00362-9
Xiaoting Hong, Zhengpeng Wang, Weimin Cai, Feng Lu, Jun Zhang, Yanzhu Yang, Na Ma, Yingjun Liu, Visible-Light-Activated Nanoparticle Photocatalyst of Iodine-Doped Titanium Dioxide Chemistry of Materials. ,vol. 17, pp. 1548- 1552 ,(2005) , 10.1021/CM047891K
Teruhisa Ohno, Toshiki Tsubota, Kazumoto Nishijima, Zenta Miyamoto, Degradation of Methylene Blue on Carbonate Species-doped TiO2 Photocatalysts under Visible Light Chemistry Letters. ,vol. 33, pp. 750- 751 ,(2004) , 10.1246/CL.2004.750