Synthesis, characterization, thermal and catalytic properties of a novel carbazole derived Azo ligand and its metal complexes

作者: Selma Bal , Joseph Donald Connolly

DOI: 10.1016/J.ARABJC.2015.11.012

关键词:

摘要: Abstract This work explains the synthesis of a new azo-Schiff base compound, derived from condensation between N-ethylcarbazole-3-carbaldehyde and 1,3-diaminopropane, followed by azo coupling reaction with diazonium salt 2-amino-4-methyl phenol. The newly synthesized was further reacted acetate salts Copper, Cobalt Nickel to give three coordination compounds. All compounds have been characterized through spectral analysis. examined for their thermal catalytic features. Good moderate yields were obtained oxidation styrene cyclohexene. Thermal features ligand its complexes explained results supported proposed structures.

参考文章(32)
Mehmet Tümer, Cumali Çelik, Hüseyin Köksal, Selahattin Serin, Transition metal complexes of bidentate Schiff base ligands Transition Metal Chemistry. ,vol. 24, pp. 525- 532 ,(1999) , 10.1023/A:1006982622965
İsmet Kaya, Musa Kamacı, Fatih Arıcan, Synthesis and characterization of polyphenols derived from 4-fluorobenzaldeyde: The effect of electron-donating group on some physical properties Journal of Applied Polymer Science. ,vol. 125, pp. 608- 619 ,(2012) , 10.1002/APP.36273
Hideyo Shindo, Theodore L. Brown, Infrared Spectra of Complexes of L-Cysteine and Related Compounds with Zinc(II), Cadmium(II), Mercury(II), and Lead(II)1 Journal of the American Chemical Society. ,vol. 87, pp. 1904- 1909 ,(1965) , 10.1021/JA01087A013
Serhan Uruş, Mecit Özdemir, Gökhan Ceyhan, Mehmet Tümer, Chemically Modified Silica-Gel With an Azo-Schiff Ligand and Its Metal Complexes With Cu(II), Co(II), Ni(II) and Mn(II): Applications as Catalysts on the Oxidation of Cyclohexane Under Microwave Power Synthesis and Reactivity in Inorganic Metal-organic and Nano-metal Chemistry. ,vol. 42, pp. 382- 391 ,(2012) , 10.1080/15533174.2011.611208
Sandeep P. Netalkar, Anupama A. Nevrekar, Vidyanand K. Revankar, Design, Synthesis and Characterization of Bimetallic Palladium Complexes for Terminal Olefin Epoxidation Catalysis Letters. ,vol. 144, pp. 1573- 1583 ,(2014) , 10.1007/S10562-014-1315-4
Felora Heshmatpour, Saeed Rayati, Mona Afghan Hajiabbas, Payam Abdolalian, Bernhard Neumüller, Copper(II) Schiff base complexes derived from 2,2′-dimethyl-propandiamine: Synthesis, characterization and catalytic performance in the oxidation of styrene and cyclooctene Polyhedron. ,vol. 31, pp. 443- 450 ,(2012) , 10.1016/J.POLY.2011.09.048
Dexuan Huang, Chaoxian Wang, Yibing Song, Immobilized complexes of the salen Schiff’s base with metal as oxidation catalysts Russian Journal of General Chemistry. ,vol. 83, pp. 2361- 2369 ,(2013) , 10.1134/S1070363213120281