A new determination of the ground state interatomic potential for He2

作者: Ronald A. Aziz , Frederick R.W. McCourt , Clement C.K. Wong

DOI: 10.1080/00268978700101941

关键词:

摘要: A simple accurate potential of the HFD-B form, which appears to be best characterization He-He interaction constructed date, is presented. It has been fitted low temperature second virial coefficient data and recent room viscosity data, while at same time pinning repulsive wall value calculated by Ceperley Partridge 1 Bohr. possesses a well depth 10·948 K, considerably deeper than many empirical or ab initio potentials. reproduces, within experimental error, such dilute gas properties as coefficients, viscosities thermal conductivities over wide range. also predicts, microscopic differential cross sections, high energy integral sections backward glory oscillations in sections. Finally, it accounts for nuclear magnetic relaxation 3He supports weakly bound state 4He interaction.

参考文章(60)
T. H. Spurling, Edward A. Mason, The virial equation of state ,(1969)
I. Finch, T. P. Murray, H. Preston-Thomas, L. G. Rubin, R. L. Shepard, Harmon H. Plumb, Temperature : its measurement and control in science and industry Instrument Society of America. ,(1972)
Kin-Chue NG, William J. Meath, A.R. Allnatt, A reliable semi-empirical approach for evaluating the isotropic intermolecular forces between closed-shell systems. Molecular Physics. ,vol. 37, pp. 237- 253 ,(1979) , 10.1080/00268977900100191
C. F. Curtiss, J. O. Hirschfelder, R. B. Bird, Molecular theory of gases and liquids ,(1954)
W. Aufm Kampe, D.E. Oates, W. Schrader, H.G. Bennewitz, Observation of the atomic Ramsauer—townsend effect in 4He4He scattering Chemical Physics Letters. ,vol. 18, pp. 323- 324 ,(1973) , 10.1016/0009-2614(73)80179-4
P. B. Foreman, P. K. Rol, K. P. Coffin, The repulsive 1 Σg+ He2 potential obtained from total cross sections Journal of Chemical Physics. ,vol. 61, pp. 1658- 1665 ,(1974) , 10.1063/1.1682159
R. Feltgen, H. Pauly, F. Torello, H. Vehmeyer, Determination of theHe4-He4Repulsive Potential up to 0.14 eV by Inversion of High-Resolution Total—Cross-Section Measurements Physical Review Letters. ,vol. 30, pp. 820- 823 ,(1973) , 10.1103/PHYSREVLETT.30.820
R. J. Munn, Francis J. Smith, E. A. Mason, L. Monchick, Transport Collision Integrals for Quantum Gases Obeying a 12–6 Potential The Journal of Chemical Physics. ,vol. 42, pp. 537- 539 ,(1965) , 10.1063/1.1695969
C. W. Clenshaw, A. R. Curtis, A method for numerical integration on an automatic computer Numerische Mathematik. ,vol. 2, pp. 197- 205 ,(1960) , 10.1007/BF01386223
Ronald A. Aziz, M.J. Slaman, On the Xe-Xe potential energy curve and related properties Molecular Physics. ,vol. 57, pp. 825- 840 ,(1986) , 10.1080/00268978600100591