Non-chondritic platinum-group element ratios in the Earth's mantle

作者: L. Pattou , J. P. Lorand , M. Gros

DOI: 10.1038/379712A0

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摘要: THE Earth's upper mantle has an overabundance of highly siderophile elements (platinum-group elements, gold and rhenium), relative to what would be expected from equilibrium with the metallic core1–3. This excess is now widely believed have been introduced as a "late veneer" by meteorite bombardment during early Earth history, but after separation core4. Here we report high-precision analyses platinum-group (PGEs) fertile upper-mantle Iherzolites, which show variations in abundances that exceed those chondritic meteorites are thought furnished late veneer5. In particular, Pd/Ir ratio, at about 1.76, significantly greater than known meteorites6. Our results, combined previous indications both non-chondritic nearly PGE ratios few other Iherzolites analysed2,3,7–11, strongly suggest heterogeneous its content on scales ∼100 kilometres. If observed can reconciled plausible meteoritic source, heterogeneity may reflect original spatial variation veneer; otherwise, additional fractionation mechanism seems required.

参考文章(29)
G.E. Brügmann, A.J. Naldrett, M. Asif, P.C. Lightfoot, N.S. Gorbachev, V.A. Fedorenko, Siderophile and chalcophile metals as tracers of the evolution of the Siberian Trap in the Noril'sk region, Russia Geochimica et Cosmochimica Acta. ,vol. 57, pp. 2001- 2018 ,(1993) , 10.1016/0016-7037(93)90089-F
Paul R. Hamlyn, Reid R. Keays, Warrington E. Cameron, Anthony J. Crawford, Helen M. Waldron, Precious metals in magnesian low-Ti lavas: Implications for metallogenesis and sulfur saturation in primary magmas Geochimica et Cosmochimica Acta. ,vol. 49, pp. 1797- 1811 ,(1985) , 10.1016/0016-7037(85)90150-4
A. Borisov, H. Palme, The solubility of iridium in silicate melts: New data from experiments with Ir10Pt90 alloys Geochimica et Cosmochimica Acta. ,vol. 59, pp. 481- 485 ,(1995) , 10.1016/0016-7037(94)00358-S
Norman J Page, Raymond W. Talkington, Palladium, platinum, rhodium, ruthenium and iridium in peridotites and chromitites from ophiolite complexes in Newfoundland Canadian Mineralogist. ,vol. 22, pp. 137- 149 ,(1984)
H. Downes, J.-L. Bodinier, M. F. Thirlwall, J.-P. Lorand, J. Fabries, REE and Sr-Nd Isotopic Geochemistry of Eastern Pyrenean Peridotite Massifs: Sub-Continental Lithospheric Mantle Modified by Continental Magmatism Journal of Petrology. ,vol. Special_Volume, pp. 97- 115 ,(1991) , 10.1093/PETROLOGY/SPECIAL_VOLUME.2.97