A low temperature in situ infrared reflected absorbance spectroelectrochemical (LT IRRAS) cell
作者： Peng Liu , Baokang Jin , Faliang Cheng
DOI: 10.1016/J.JELECHEM.2007.02.012
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摘要: Abstract The design and tests of a low temperature optically reflected absorbance cell for in situ FTIR spectroelectrochemistry is discussed. It works very well the range from −100 to +25 °C with control precision within ±0.5 °C. facile cleaning convenient manipulation. Besides, it can work, successively, long time filling Dewar flask liquid N2. electrochemical performance characterized cyclic voltammetry K4Fe(CN)6 at room steady-state ferrocene temperature. applicability demonstrated observe electrogenerated intermediate 1,4-bis(2-ferrocenylvinyl)benzene (p-(Fc–CH CH)2BZ).
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