Ionic Conductivity of Network Polymers from Poly(ethylene oxide) Containing Lithium Perchlorate
作者： Masayoshi Watanabe , Satoshi Nagano , Kohei Sanui , Naoya Ogata
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摘要: The structure-conductivity relationships were investigated on the network polymers from poly(ethylene oxide)(PEO) containing lithium perchlorate (LiClO4), in contrast to polymer complex formed by linear PEO and LiClO4. crosslinked structure caused a considerable decrease degree of crystallinity resulting PEO–LiClO4 complexes, which contributed high ionic conductivity. Li+ ions demonstrated as mobile species these while ClO4− somewhat conductivity order 10−5 Scm1 at 30°C was attained [LiClO4]/[EO unit] =0.02.
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