Application of Filtered Model for Reacting Gas–Solid Flows and Optimization in a Large-Scale Methanol-to-Olefin Fluidized-Bed Reactor

作者: Li-Tao Zhu , Mao Ye , Zheng-Hong Luo

DOI: 10.1021/ACS.IECR.6B02819

关键词:

摘要: A reactor model for a methanol-to-olefin (MTO) reaction system was constructed by incorporating filtered drag model, gas–solid heat-transfer and an MTO kinetic to probe large-scale behavior explore optimization. First, the efficiency of several typical models evaluated comparing predicted results with experimental data. Second, effect two significant operation parameters, namely, temperature water-to-methanol ratio, were studied based on above-mentioned model. Predictions suggested optimum catalyst residence time (∼33 min) average coke content (∼6.74%) this system. In addition, relatively high maximized ethylene production, water introduced into feed significantly attenuated deposition. This work is first conduct coarse-grid simulations using developed effective filtered-CFD coupled flow optimizat...

参考文章(55)
Nan Xie, Francine Battaglia, Sreekanth Pannala, Effects of using two- versus three-dimensional computational modeling of fluidized beds: Part I, hydrodynamics Powder Technology. ,vol. 182, pp. 1- 13 ,(2008) , 10.1016/J.POWTEC.2007.07.005
Lei Ying, Xiaoshuai Yuan, Mao Ye, Youwei Cheng, Xi Li, Zhongmin Liu, A seven lumped kinetic model for industrial catalyst in DMTO process Chemical Engineering Research & Design. ,vol. 100, pp. 179- 191 ,(2015) , 10.1016/J.CHERD.2015.05.024
Shailesh S. Ozarkar, Xiaokang Yan, Shuyan Wang, Christian C. Milioli, Fernando E. Milioli, Sankaran Sundaresan, Validation of filtered two-fluid models for gas–particle flows against experimental data from bubbling fluidized bed Powder Technology. ,vol. 284, pp. 159- 169 ,(2015) , 10.1016/J.POWTEC.2015.06.028
Nan Zhang, Bona Lu, Wei Wang, Jinghai Li, Virtual experimentation through 3D full-loop simulation of a circulating fluidized bed Particuology. ,vol. 6, pp. 529- 539 ,(2008) , 10.1016/J.PARTIC.2008.07.013
Ana G Gayubo, Andrés T Aguayo, Ana E Sánchez del Campo, Ana M Tarrío, Javier Bilbao, None, Kinetic Modeling of Methanol Transformation into Olefins on a SAPO-34 Catalyst Industrial & Engineering Chemistry Research. ,vol. 39, pp. 292- 300 ,(2000) , 10.1021/IE990188Z
D.J. Gunn, Transfer of heat or mass to particles in fixed and fluidised beds International Journal of Heat and Mass Transfer. ,vol. 21, pp. 467- 476 ,(1978) , 10.1016/0017-9310(78)90080-7
Simon Schneiderbauer, Stefan Puttinger, Stefan Pirker, Pablo Aguayo, Vasileios Kanellopoulos, CFD modeling and simulation of industrial scale olefin polymerization fluidized bed reactors Chemical Engineering Journal. ,vol. 264, pp. 99- 112 ,(2015) , 10.1016/J.CEJ.2014.11.058
Jinsen Gao, Xingying Lan, Yiping Fan, Jian Chang, Gang Wang, Chunxi Lu, Chunming Xu, CFD modeling and validation of the turbulent fluidized bed of FCC particles Aiche Journal. ,vol. 55, pp. 1680- 1694 ,(2009) , 10.1002/AIC.11824
Peng Tian, Yingxu Wei, Mao Ye, Zhongmin Liu, Methanol to Olefins (MTO): From Fundamentals to Commercialization ACS Catalysis. ,vol. 5, pp. 1922- 1938 ,(2015) , 10.1021/ACSCATAL.5B00007
De Chen, Kjell Moljord, Terje Fuglerud, Anders Holmen, The effect of crystal size of SAPO-34 on the selectivity and deactivation of the MTO reaction Microporous and Mesoporous Materials. ,vol. 29, pp. 191- 203 ,(1999) , 10.1016/S1387-1811(98)00331-X