Anti-glass phases and other lanthanide tellurates with fluorite-related structures

作者: M. Trömel , W. Hützler , E. Münch

DOI: 10.1016/0022-5088(85)90352-2

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摘要: Abstract Two series of metastable, cubic face-centered non-stoichiometric anti-glass tellurates Y, La, and lanthanides have been found: Te-richer phases, containing tetravalent Te only, with compositions between Ln 2 6 O 15 4 7 20 lattice constants 570−549 pm, Ln-richer phases minor amounts hexavalent Te, Ln:Te ratios 3:2 11:10, 574 539 pm.

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