Chapter 2 Addition of Unsaturated Compounds to Each Other
作者： P. Beltrame
DOI: 10.1016/S0069-8040(08)70193-6
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摘要: Publisher Summary This chapter discusses the addition of unsaturated compounds to each other (the Diels-Alder reaction and cycloadditions). Kinetic data on reactions their implications as mechanism is also discussed in chapter. Two popular reactions, dimerisation cyclopentadiene endo-dicyclopentadiene that butadiene 4-vinylcyclohexene are suitable for a comparison experimental results. Rate coefficients from 8 different sources former pure liquid phase at various temperatures (in range where possible) given The all extrapolated zero time, both secondary variation environment during cause drift observed values k. gas tabulated. Theoretical quantitative treatments cycloadditions mainly concern reaction.
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