Lanthanum hydroxide: a highly efficient and selective adsorbent for arsenate removal from aqueous solution

作者: Yulong Wang , Yanhong Liu , Tianqi Guo , Hupeng Liu , Jiale Li

DOI: 10.1007/S11356-020-10240-1

关键词:

摘要: In the present work, a lanthanum hydroxide adsorbent was prepared by simple precipitation process, and its arsenic removal performances adsorption mechanisms were investigated batch experiments various techniques including field emission scanning electron microscopy with energy-dispersive X-ray spectrophotometry (FESEM-EDX), Brunauer-Emmett-Teller (BET) analysis, powder diffraction (p-XRD), Fourier transform infrared spectroscopy (FTIR), photoelectron (XPS). The influence of pH on showed that can effectively remove As(V) from solution, whereas As(III) very low, indicating selectively but not As(III). isotherm study maximum capacities at 5.0 9.0 299.4 192.3 mg/g, respectively, much higher than those widely used ferrihydrite. Significant interference caused presence phosphate natural organic acids (NOAs), such as citric acid. Powder XRD, FTIR, XPS analysis almost transformed into arsenate after 4.0, while portion remained 6.0 9.0. Furthermore, ligand exchange between hydroxyl groups formation inner-sphere surface complexes could play central role in which needs further investigation.

参考文章(45)
Ling Yu, Ying Ma, Choon Nam Ong, Jianping Xie, Yanbiao Liu, None, Rapid adsorption removal of arsenate by hydrous cerium oxide–graphene composite RSC Advances. ,vol. 5, pp. 64983- 64990 ,(2015) , 10.1039/C5RA08922K
Rong Shi, Yongfeng Jia, Chengzhi Wang, Shuhua Yao, Mechanism of arsenate mobilization from goethite by aliphatic carboxylic acid. Journal of Hazardous Materials. ,vol. 163, pp. 1129- 1133 ,(2009) , 10.1016/J.JHAZMAT.2008.07.068
Huijie Zhu, Yongfeng Jia, Xing Wu, He Wang, Removal of arsenic from water by supported nano zero-valent iron on activated carbon Journal of Hazardous Materials. ,vol. 172, pp. 1591- 1596 ,(2009) , 10.1016/J.JHAZMAT.2009.08.031
Line Dithmer, Andrew S. Lipton, Kasper Reitzel, Terence E. Warner, Daniel Lundberg, Ulla Gro Nielsen, Characterization of phosphate sequestration by a lanthanum modified bentonite clay: a solid-state NMR, EXAFS, and PXRD study. Environmental Science & Technology. ,vol. 49, pp. 4559- 4566 ,(2015) , 10.1021/ES506182S
Jie Xie, Zhe Wang, Shaoyong Lu, Deyi Wu, Zhenjia Zhang, Hainan Kong, Removal and recovery of phosphate from water by lanthanum hydroxide materials Chemical Engineering Journal. ,vol. 254, pp. 163- 170 ,(2014) , 10.1016/J.CEJ.2014.05.113
Peter J. Swedlund, Hannah Holtkamp, Yantao Song, Christopher J. Daughney, Arsenate-ferrihydrite systems from minutes to months: a macroscopic and ir spectroscopic study of an elusive equilibrium. Environmental Science & Technology. ,vol. 48, pp. 2759- 2765 ,(2014) , 10.1021/ES404742C
Yu Zhang, Min Yang, Xiao-Min Dou, Hong He, Dong-Sheng Wang, Arsenate adsorption on an Fe-Ce bimetal oxide adsorbent: Role of surface properties Environmental Science & Technology. ,vol. 39, pp. 7246- 7253 ,(2005) , 10.1021/ES050775D
Gao-Sheng Zhang, Jiu-Hui Qu, Hui-Juan Liu, Rui-Ping Liu, Guo-Ting Li, Removal Mechanism of As(III) by a Novel Fe−Mn Binary Oxide Adsorbent: Oxidation and Sorption Environmental Science & Technology. ,vol. 41, pp. 4613- 4619 ,(2007) , 10.1021/ES063010U
Yongfeng Jia, George P. Demopoulos, Adsorption of arsenate onto ferrihydrite from aqueous solution: influence of media (sulfate vs nitrate), added gypsum, and pH alteration. Environmental Science & Technology. ,vol. 39, pp. 9523- 9527 ,(2005) , 10.1021/ES051432I
Gaosheng Zhang, Jiuhui Qu, Huijuan Liu, Ruiping Liu, Rongcheng Wu, Preparation and evaluation of a novel Fe-Mn binary oxide adsorbent for effective arsenite removal Water Research. ,vol. 41, pp. 1921- 1928 ,(2007) , 10.1016/J.WATRES.2007.02.009