Aqueous Biphasic Systems of Pyrrolidinium Ionic Liquids with Organic Acid-Derived Anions and K3PO4

作者: Karen G. João , Liliana C. Tomé , Andreia S. L. Gouveia , Isabel M. Marrucho

DOI: 10.1021/ACS.JCED.6B00487

关键词:

摘要: Aqueous biphasic systems based on ionic liquids (ILs) have been researched as promising extraction and purification routes for a huge diversity of compounds. The inherent tunability offered by ILs combined with the large variety salts available underlines reliable phase equilibrium data. In this vein, work presents novel aqueous 1-butyl-1-methylpyrrolidinium cation anions derived from organic acids, such acetate, trifluoroacetate, hexanoate, adipate, one halogenated anion, bromide, in presence powerful salting out species, inorganic salt K3PO4. capacity these to undergo separation is discussed regard chemical structure IL anion. results here obtained were compared those determined poly(ionic liquid) analogues, it was observed that while hydrophobicity anion has major role splitting, liquid)s played polymer molecular ...

参考文章(60)
Ana Filipa M. Cláudio, Lorna Swift, Jason P. Hallett, Tom Welton, João A. P. Coutinho, Mara G. Freire, Extended scale for the hydrogen-bond basicity of ionic liquids Physical Chemistry Chemical Physics. ,vol. 16, pp. 6593- 6601 ,(2014) , 10.1039/C3CP55285C
Zhuo Du, Yong-Liang Yu, Jian-Hua Wang, Extraction of Proteins from Biological Fluids by Use of an Ionic Liquid/Aqueous Two‐Phase System Chemistry: A European Journal. ,vol. 13, pp. 2130- 2137 ,(2007) , 10.1002/CHEM.200601234
Catarina M. S. S. Neves, Mara G. Freire, João A. P. Coutinho, Improved recovery of ionic liquids from contaminated aqueous streams using aluminium-based salts{ RSC Advances. ,vol. 2, pp. 10882- 10890 ,(2012) , 10.1039/C2RA21535G
João H. Santos, Francisca A. e Silva, Sónia P. M. Ventura, João A. P. Coutinho, Ranyere L. de Souza, Cleide M. F. Soares, Álvaro S. Lima, Ionic liquid-based aqueous biphasic systems as a versatile tool for the recovery of antioxidant compounds. Biotechnology Progress. ,vol. 31, pp. 70- 77 ,(2015) , 10.1002/BTPR.2000
Matheus M Pereira, Sónia N Pedro, Maria V Quental, Álvaro S Lima, João AP Coutinho, Mara G Freire, None, Enhanced extraction of bovine serum albumin with aqueous biphasic systems of phosphonium- and ammonium-based ionic liquids. Journal of Biotechnology. ,vol. 206, pp. 17- 25 ,(2015) , 10.1016/J.JBIOTEC.2015.03.028
Agnieszka Brandt, John Gräsvik, Jason P Hallett, Tom Welton, None, Deconstruction of lignocellulosic biomass with ionic liquids Green Chemistry. ,vol. 15, pp. 550- 583 ,(2013) , 10.1039/C2GC36364J
Tânia E. Sintra, Rafaela Cruz, Sónia P.M. Ventura, João A.P. Coutinho, Phase diagrams of ionic liquids-based aqueous biphasic systems as a platform for extraction processes The Journal of Chemical Thermodynamics. ,vol. 77, pp. 206- 213 ,(2014) , 10.1016/J.JCT.2013.10.024
Maria V Quental, Helena Passos, Kiki A Kurnia, João AP Coutinho, Mara G Freire, None, Aqueous biphasic systems composed of ionic liquids and acetate-based salts: phase diagrams, densities and viscosities. Journal of Chemical & Engineering Data. ,vol. 60, pp. 1674- 1682 ,(2015) , 10.1021/JE501044U
Hugo F. D. Almeida, Mara G. Freire, Isabel M. Marrucho, Improved extraction of fluoroquinolones with recyclable ionic-liquid-based aqueous biphasic systems Green Chemistry. ,vol. 18, pp. 2717- 2725 ,(2016) , 10.1039/C5GC02464A
Isabel M. Marrucho, Mara G. Freire, Aqueous Biphasic Systems Based on Ionic Liquids for Extraction, Concentration and Purification Approaches Green Chemistry and Sustainable Technology. pp. 91- 119 ,(2016) , 10.1007/978-3-662-48520-0_5