Catalytic Transfer Hydrogenation of Biomass-Derived Ethyl Levulinate into Gamma-Valerolactone Over Graphene Oxide-Supported Zirconia Catalysts
作者： Jinhua Lai , Shuolin Zhou , Xianxiang Liu , Yongjun Yang , Jing Lei
DOI: 10.1007/S10562-019-02835-2
关键词:
摘要: The transformation of biomass-derived intermediates into value-added chemicals and liquid fuels is great importance in sustainable chemistry. In this study, graphene oxide supported ZrO2 (ZrO2/GO) was found to be an active heterogeneous catalyst for the transfer hydrogenation ethyl levulinate γ-valerolactone (GVL) with iso-propanol as hydrogen donor. Several important reaction parameters such donor, temperature loading were studied detail aim get a high yield GVL. It that structure alcohols had effect towards activity ZrO2/GO selectivity Iso-propanol best donor highest GVL reached 91.7% conversion 96.2% under optimal conditions. More importantly, demonstrated stability without loss its catalytic during recycling experiments, which should due strong interaction between GO ZrO2. showed up 91.7%.
springer.com
sci-hub.se 参考文章(24)
Suveen Kumar, Saurabh Kumar, Sachchidanand Tiwari, Saurabh Srivastava, Manish Srivastava, Birendra Kumar Yadav, Saroj Kumar, Thien Toan Tran, Ajay Kumar Dewan, Ashok Mulchandani, Jai Gopal Sharma, Sagar Maji, Bansi Dhar Malhotra, None, Biofunctionalized Nanostructured Zirconia for Biomedical Application: A Smart Approach for Oral Cancer Detection Advanced Science. ,vol. 2, pp. 1500048- 1500048 ,(2015) , 10.1002/ADVS.201500048
Fan-Xin Zeng, Hai-Feng Liu, Li Deng, Bing Liao, Hao Pang, Qing-Xiang Guo, Ionic-Liquid-Catalyzed Efficient Transformation of γ-Valerolactone to Methyl 3-Pentenoate under Mild Conditions Chemsuschem. ,vol. 6, pp. 600- 603 ,(2013) , 10.1002/CSSC.201200841
Xing Tang, Lei Hu, Yong Sun, Geng Zhao, Weiwei Hao, Lu Lin, None, Conversion of biomass-derived ethyl levulinate into γ-valerolactone via hydrogen transfer from supercritical ethanol over a ZrO2 catalyst RSC Advances. ,vol. 3, pp. 10277- 10284 ,(2013) , 10.1039/C3RA41288A
Mei Chia, James A. Dumesic, Liquid-phase catalytic transfer hydrogenation and cyclization of levulinic acid and its esters to γ-valerolactone over metal oxide catalysts Chemical Communications. ,vol. 47, pp. 12233- 12235 ,(2011) , 10.1039/C1CC14748J
Yuji Kubo, Daiki Kakizaki, Makiko Kogo, Yasuhiro Magatani, Water-dispersible boronate nanoparticles as support materials for noble metals in the hydrogenation of levulinic acid to γ-valerolactone Supramolecular Chemistry. ,vol. 28, pp. 91- 97 ,(2016) , 10.1080/10610278.2015.1086764
Wenjing Yang, Haiyang Cheng, Bin Zhang, Yan Li, Tong Liu, Mingli Lan, Yancun Yu, Chao Zhang, Weiwei Lin, Shin-ichiro Fujita, Masahiko Arai, Fengyu Zhao, Hydrogenation of levulinic acid by RuCl2(PPh3)3 in supercritical CO2: the significance of structural changes of Ru complexes via interaction with CO2 Green Chemistry. ,vol. 18, pp. 3370- 3377 ,(2016) , 10.1039/C6GC00019C
Ying Yang, Cheng-Jun Sun, Dennis E. Brown, Liqiang Zhang, Feng Yang, Hairui Zhao, Yue Wang, Xiaohui Ma, Xin Zhang, Yang Ren, A smart strategy to fabricate Ru nanoparticle inserted porous carbon nanofibers as highly efficient levulinic acid hydrogenation catalysts Green Chemistry. ,vol. 18, pp. 3558- 3566 ,(2016) , 10.1039/C5GC02802G
Zehui Zhang, Synthesis of γ-Valerolactone from Carbohydrates and its Applications. Chemsuschem. ,vol. 9, pp. 156- 171 ,(2016) , 10.1002/CSSC.201501089
Matthew J. Gilkey, Bingjun Xu, Heterogeneous Catalytic Transfer Hydrogenation as an Effective Pathway in Biomass Upgrading ACS Catalysis. ,vol. 6, pp. 1420- 1436 ,(2016) , 10.1021/ACSCATAL.5B02171
Robert-Jan van Putten, Jan C. van der Waal, Ed de Jong, Hero J. Heeres, Reactivity studies in water on the acid-catalysed dehydration of psicose compared to other ketohexoses into 5-hydroxymethylfurfural Carbohydrate Research. ,vol. 446, pp. 1- 6 ,(2017) , 10.1016/J.CARRES.2017.04.009