Radiochemical study of reaction of trichlorogermane with carbon tetrachloride

摘要: 1. The reaction of trichlorogermane with CCl4 at 75° leads mainly to the formation HCCl3 and GeCl4. The yield CCl3GeCl3 under these conditions is 17%, in which connection its formation, based on radiochemical study data, proceeds by carbenoid mechanism, i.e., via transfer GeCl2 from CCl4. 2. The participation HGeCl3 as a possible intermediate compound complex C4H8O2·GeCl2 CCl4, probably other organic halides, should be rejected.