Main-Group Metallomimetics: Transition Metal-like Photolytic CO Substitution at Boron.
作者： Holger Braunschweig , Ivo Krummenacher , Marc-André Légaré , Alexander Matler , Krzysztof Radacki
DOI: 10.1021/JACS.6B13047
关键词:
摘要: The carbon monoxide adduct of an unhindered and highly reactive CAAC-bound arylborylene, [(CAAC)B(CO)Ar] (CAAC = cyclic (alkyl) (amino)carbene), has been prepared using a transfer reaction from the linear iron borylene complex [(PMe3) (CO)3Fe=BAr]. is source dicoordinate [(CAAC)ArB:] that can be liberated by selective photolytic CO extrusion that, although reactive, sufficiently long-lived to react intermolecularly. Through trapping generated in this manner, we present, among others, first metal-free borylene(I) species containing nitrogen-based donor, as well new boron-containing radical.
acs.org
sci-hub.se 参考文章(40)
M.-A. Legare, M.-A. Courtemanche, E. Rochette, F.-G. Fontaine, Metal-free catalytic C-H bond activation and borylation of heteroarenes Science. ,vol. 349, pp. 513- 516 ,(2015) , 10.1126/SCIENCE.AAB3591
Holger Braunschweig, Rian D. Dewhurst, Florian Hupp, Marco Nutz, Krzysztof Radacki, Christopher W. Tate, Alfredo Vargas, Qing Ye, Multiple complexation of CO and related ligands to a main-group element Nature. ,vol. 522, pp. 327- 330 ,(2015) , 10.1038/NATURE14489
Douglas W. Stephan, Gerhard Erker, Frustrated Lewis pair chemistry: development and perspectives. Angewandte Chemie. ,vol. 54, pp. 6400- 6441 ,(2015) , 10.1002/ANIE.201409800
Philipp Bissinger, Holger Braunschweig, Katharina Kraft, Thomas Kupfer, Trapping the Elusive Parent Borylene Angewandte Chemie. ,vol. 50, pp. 4704- 4707 ,(2011) , 10.1002/ANIE.201007543
Michèle Soleilhavoup, Guy Bertrand, Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise Accounts of Chemical Research. ,vol. 48, pp. 256- 266 ,(2015) , 10.1021/AR5003494
Holger Braunschweig, Rian D. Dewhurst, Achim Schneider, Electron-precise coordination modes of boron-centered ligands. Chemical Reviews. ,vol. 110, pp. 3924- 3957 ,(2010) , 10.1021/CR900333N
Maik Finze, Eduard Bernhardt, Annegret Terheiden, Michael Berkei, Helge Willner, Dines Christen, Heinz Oberhammer, Friedhelm Aubke, Tris(trifluoromethyl)borane carbonyl, (CF3)3BCO-synthesis, physical, chemical and spectroscopic properties, gas phase, and solid state structure. Journal of the American Chemical Society. ,vol. 124, pp. 15385- 15398 ,(2002) , 10.1021/JA0209924
G. C. Welch, R. R. S. Juan, J. D. Masuda, D. W. Stephan, Reversible, Metal-Free Hydrogen Activation Science. ,vol. 314, pp. 1124- 1126 ,(2006) , 10.1126/SCIENCE.1134230
Holger Braunschweig, Theresa Dellermann, Rian D. Dewhurst, William C. Ewing, Kai Hammond, J. Oscar C. Jimenez-Halla, Thomas Kramer, Ivo Krummenacher, Jan Mies, Ashwini K. Phukan, Alfredo Vargas, Metal-free binding and coupling of carbon monoxide at a boron–boron triple bond Nature Chemistry. ,vol. 5, pp. 1025- 1028 ,(2013) , 10.1038/NCHEM.1778
Geoffrey H. Spikes, James C. Fettinger, Philip P. Power, Facile activation of dihydrogen by an unsaturated heavier main group compound. Journal of the American Chemical Society. ,vol. 127, pp. 12232- 12233 ,(2005) , 10.1021/JA053247A