Novel triazole bearing zinc(II) and magnesium(II) metallo-phthalocyanines: Synthesis, characterization, photophysical and photochemical properties
作者： Hakkı Türker Akçay , Mehmet Pişkin , Ümit Demirbaş , Rıza Bayrak , Mahmut Durmuş
DOI: 10.1016/J.JORGANCHEM.2013.08.029
关键词:
摘要: The synthesis and characterization of novel tetrakis N-(3,5-dichlorophenyl)-5-methyl-3H-1,2,4-triazol-3-one (1) N-(3,5-dichlorophenyl)-5-ethyl-3H-1,2,4-triazol-3-one (2) substituted phthalonitrile derivatives their new organosoluble peripherally tetra-substituted zinc(II) (6 7) magnesium(II) (8 9) phthalocyanines were studied in this study. Photophysical photochemical data these compounds measured dimethysulfoxide (DMSO). phthalocyanine showed excellent fluorescent properties the corresponding generated efficient singlet oxygen. fluorescence quenching behavior tetra-peripherally by addition 1,4-benzoquinone also DMSO. These molecules can distinctly be employed field photodynamic therapy combination with imaging.
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