Red Color GeSe2‐Based Chalcohalide Glasses for Infrared Optics

作者: Zhiyong Yang , Lan Luo , Wei Chen

DOI: 10.1111/J.1551-2916.2006.01006.X

关键词:

摘要: GeSe2–Ga2Se3–CsI chalcohalide glasses are synthesized, and their optical properties thermo-mechanical studied. A typical characteristic of the is excellent transparency in red-light region addition to 8–14 μm atmospheric window, which vital importance quality control infrared systems. The short-wavelength absorption edge λs glass system has a distinct blue shift with increasing CsI content, physicochemical interpretations suggested formulated. These present transition temperature (Tg) around 300°C good thermal stability. Consequently, they can be promising candidate materials for optics, although hardness relatively weak.

参考文章(9)
Xianghua Zhang, Hongli Ma, Jacques Lucas, Yann Guimond, Stéphanie Kodjikian, None, Optical fibers and molded optics in infrared transparent glass-ceramic Journal of Non-crystalline Solids. ,vol. 336, pp. 49- 52 ,(2004) , 10.1016/J.JNONCRYSOL.2003.12.059
A. Giridhar, Sudha Mahadevan, Chemical ordering in GeGaSe glasses Journal of Non-crystalline Solids. ,vol. 126, pp. 161- 169 ,(1990) , 10.1016/0022-3093(90)91034-O
Hongli Ma, Xianghua Zhang, Jacques Lucas, None, Infrared transmitting chalcogenide glass ceramics Journal of Non-crystalline Solids. ,vol. 317, pp. 270- 274 ,(2003) , 10.1016/S0022-3093(02)01819-7
P. Boolchand, M. F. Thorpe, Glass-forming tendency, percolation of rigidity, and onefold-coordinated atoms in covalent networks. Physical Review B. ,vol. 50, pp. 10366- 10368 ,(1994) , 10.1103/PHYSREVB.50.10366
H.L Ma, Y Guimond, X.H Zhang, J Lucas, Ga–Ge–Sb–Se based glasses and influence of alkaline halide addition Journal of Non-crystalline Solids. ,vol. 256, pp. 165- 169 ,(1999) , 10.1016/S0022-3093(99)00472-X
X.H. Zhang, Y. Guimond, Y. Bellec, Production of complex chalcogenide glass optics by molding for thermal imaging Journal of Non-crystalline Solids. ,vol. 326, pp. 519- 523 ,(2003) , 10.1016/S0022-3093(03)00464-2
Haizheng Tao, Shun Mao, Wei Tong, Xiujian Zhao, Formation and properties of the GeS2–In2S3–KCl new chalcohalide glassy system Materials Letters. ,vol. 60, pp. 741- 745 ,(2006) , 10.1016/J.MATLET.2005.10.003
Xianghua Zhang, MA Hongli, Jacques Lucas, None, A new class of infrared transmitting glass-ceramics based on controlled nucleation and growth of alkali halide in a sulphide based glass matrix Journal of Non-crystalline Solids. ,vol. 337, pp. 130- 135 ,(2004) , 10.1016/J.JNONCRYSOL.2004.03.119
Zhao Donghui, Xia Fang, Chen Guorong, Zhang Xianghua, Ma Hongli, JL Adam, None, Formation and properties of chalcogenide glasses in the GeSe2-As2Se3-CdSe system Journal of the American Ceramic Society. ,vol. 88, pp. 3143- 3146 ,(2005) , 10.1111/J.1551-2916.2005.00590.X