Comparison of solution processed As33S67 thin films deposited using primary amines of various aliphatic chain length

作者: Jiri Jancalek , Karel Palka , Michal Kurka , Stanislav Slang , Miroslav Vlcek

DOI: 10.1016/J.JNONCRYSOL.2020.120382

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摘要: Abstract Solution processed thin chalcogenide films gain attention due to their interesting optical properties and simplicity of the deposition. The influence aliphatic chain length in primary amines used for As33S67 deposition by spin-coating subsequent characterization had been studied this paper, particularly prepared from solutions based on n-propylamine, n-butylamine, n-pentylamine n-hexylamine were investigated. As-prepared annealed at temperatures below glass Tg. Results gave evidence that variety physical chemical influences required conditions process film only (such as source dissolution time, thickness, thickness shrinkage). structure, properties, surface roughness, organic residual content resistance deposited are not significantly influenced amine but mostly post-deposition annealing temperature. Thin composition remains uninfluenced neither nor

参考文章(27)
Daimay Lin-Vien, Norman B. Colthup, William G. Fateley, Jeanette G. Grasselli, Compounds Containing –NH 2, –NHR, and –NR 2 Groups The Handbook of Infrared and Raman Characteristic Frequencies of Organic Molecules. pp. 155- 178 ,(1991) , 10.1016/B978-0-08-057116-4.50016-X
S. Slang, K. Palka, L. Loghina, A. Kovalskiy, H. Jain, M. Vlcek, Mechanism of the dissolution of As–S chalcogenide glass in n-butylamine and its influence on the structure of spin coated layers Journal of Non-crystalline Solids. ,vol. 426, pp. 125- 131 ,(2015) , 10.1016/J.JNONCRYSOL.2015.07.009
J. Cook, S. Slang, R. Golovchak, H. Jain, M. Vlcek, A. Kovalskiy, Structural features of spin-coated thin films of binary AsxS 100 − x chalcogenide glass system Thin Solid Films. ,vol. 589, pp. 642- 648 ,(2015) , 10.1016/J.TSF.2015.06.049
G. C. Chern, I. Lauks, Spin coated amorphous chalcogenide films: Structural characterization Journal of Applied Physics. ,vol. 54, pp. 2701- 2705 ,(1983) , 10.1063/1.332294
G. C. Chern, I. Lauks, Spin‐coated amorphous chalcogenide films Journal of Applied Physics. ,vol. 53, pp. 6979- 6982 ,(1982) , 10.1063/1.330043
T. Kohoutek, T. Wagner, Mir. Vlcek, Mil. Vlcek, M. Frumar, Spin-coated As33S67−xSex thin films: the effect of annealing on structure and optical properties Journal of Non-crystalline Solids. ,vol. 352, pp. 1563- 1566 ,(2006) , 10.1016/J.JNONCRYSOL.2005.09.040
Maike Waldmann, J. David Musgraves, Kathleen Richardson, Craig B. Arnold, Structural properties of solution processed Ge23Sb7S70 glass materials Journal of Materials Chemistry. ,vol. 22, pp. 17848- 17852 ,(2012) , 10.1039/C2JM32235H