Low-energy hydrogen ion shower (LEHIS) treatment of polytetrafluoroethylene (PTFE) materials

作者: Hernando S. Salapare , Gene Q. Blantocas , Virginia R. Noguera , Henry J. Ramos

DOI: 10.1016/J.APSUSC.2008.08.079

关键词:

摘要: Abstract The wettability and optical transmittance properties of hydrogen ion treated polytetrafluoroethylene (PTFE) materials were evaluated using contact angle, laser irradiation, scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) tests. processed low-energy shower (LEHIS) produced by a gas discharge source (GDIS). duration treatment energy varied to determine their effects on the PTFE specimens. Mass spectrometry showed constituents be H+ H2+ species. Within bounds conditions, flux density for Hn+ beam measured minimum 0.06 A/m2 maximum 0.25 A/m2. Both one- two-way analysis variance employed assist in interpretation empirical data. Results that lower plasma currents (Id) improved material hydrophobicity with angles measuring high 115° while higher Id resulted enhanced hydrophilicity reducing down 61°. Transmittance found correlate, i.e., surface made more wettable became optically transmissive allowing as much 99% signal transmittance. Conversely, hydrophobic reduced light leakage low 60%. As increased striations, its transmittance, wettability, tension also increased. With no observable shifting IR-absorption peaks, modification was essentially morphological character.

参考文章(31)
Ernesto Occhiello, Marco Morra, Fabio Garbassi, Polymer Surfaces: From Physics to Technology ,(1994)
Norman B. Colthup, Lawrence H. Daly, Stephen E. Wiberley, Introduction to Infrared and Raman Spectroscopy ,(1964)
D.Y Kwok, A.W Neumann, Contact angle interpretation in terms of solid surface tension Colloids and Surfaces A: Physicochemical and Engineering Aspects. ,vol. 161, pp. 31- 48 ,(2000) , 10.1016/S0927-7757(99)00323-4
Eun-Young Kim, Ju-Shik Kong, Seung-Kook An, Han-Do Kim, Surface modification of polymers and improvement of the adhesion between evaporated copper metal film and a polymer. I. Chemical modification of PET Journal of Adhesion Science and Technology. ,vol. 14, pp. 1119- 1130 ,(2000) , 10.1163/156856100743121
Henry J. Ramos, Jonathan Lee C. Monasterial, Gene Q. Blantocas, Effect of low energy ion beam irradiation on wettability of narra (Pterocarpus indicus) wood chips Nuclear Instruments & Methods in Physics Research Section B-beam Interactions With Materials and Atoms. ,vol. 242, pp. 41- 44 ,(2006) , 10.1016/J.NIMB.2005.08.003
Gene Q. Blantocas, Henry J. Ramos, Motoi Wada, Surface Modification of Narra Wood (Pterocarpus indicus) by Ion Shower Treatment Japanese Journal of Applied Physics. ,vol. 45, pp. 8498- 8501 ,(2006) , 10.1143/JJAP.45.8498
A. Satyaprasad, V. Jain, S.K. Nema, Deposition of superhydrophobic nanostructured Teflon-like coating using expanding plasma arc Applied Surface Science. ,vol. 253, pp. 5462- 5466 ,(2007) , 10.1016/J.APSUSC.2006.12.085
Mark Strobel, Neal Sullivan, Melvyn C. Branch, John Park, Michael Ulsh, Ronald S. Kapaun, Beth Leys, Surface modification of polypropylene film using N2O-containing flames Journal of Adhesion Science and Technology. ,vol. 14, pp. 1243- 1264 ,(2000) , 10.1163/156856100742186
Y Xin, Z.Y Ning, C Ye, X.H Lu, S.L Xiang, W Du, S Huang, J Chen, S.H Cheng, Optical emission study of CH4+CHF3 ECR plasma and properties of a-C:F:H films Surface & Coatings Technology. ,vol. 173, pp. 172- 177 ,(2003) , 10.1016/S0257-8972(03)00624-8