Two Novel Carbazole Dyes for Dye-Sensitized Solar Cells with Open-Circuit Voltages up to 1 V Based on Br−/Br3− Electrolytes
作者： Chao Teng , Xichuan Yang , Chunze Yuan , Chaoyan Li , Ruikui Chen
DOI: 10.1021/OL9022936
关键词:
摘要: Dye-sensitized solar cells (DSCs) based on two novel carbazole dyes (TC301 and TC306) a Br−/Br3− redox mediator in dried CH3CN solutions as electrolytes yielded Voc of 1.156 V η value 3.68% 0.939 5.22% under simulated AM 1.5, respectively. The TC301 TC306 have more positive HOMO levels (1.59 1.38 vs NHE) than the potential Br−/Br3−-based electrolytes, which sufficient driving force to regenerate dyes. Under similar conditions with an I−/I3− instead mediator, DSCs sensitized by produced 0.696 2.36% 0.621 4.10%,
acs.org
core.ac.uk 
sci-hub.se 参考文章(13)
Gareth Redmond, Donald Fitzmaurice, Spectroscopic determination of flatband potentials for polycrystalline titania electrodes in nonaqueous solvents The Journal of Physical Chemistry. ,vol. 97, pp. 1426- 1430 ,(1993) , 10.1021/J100109A029
Gerrit Boschloo, Leif Häggman, Anders Hagfeldt, Quantification of the effect of 4-tert-butylpyridine addition to I-/I3- redox electrolytes in dye-sensitized nanostructured TiO2 solar cells. Journal of Physical Chemistry B. ,vol. 110, pp. 13144- 13150 ,(2006) , 10.1021/JP0619641
Brian O'Regan, Michael Grätzel, A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films Nature. ,vol. 353, pp. 737- 740 ,(1991) , 10.1038/353737A0
Henrik Lindström, Sven Södergren, Anita Solbrand, Håkan Rensmo, Johan Hjelm, Anders Hagfeldt, Sten-Eric Lindquist, Li+ Ion Insertion in TiO2 (Anatase). 2. Voltammetry on Nanoporous Films Journal of Physical Chemistry B. ,vol. 101, pp. 7717- 7722 ,(1997) , 10.1021/JP970490Q
Akihiro Furube, Ryuzi Katoh, Kohjiro Hara, Tadatake Sato, Shigeo Murata, Hironori Arakawa, M. Tachiya, Lithium ion effect on electron injection from a photoexcited coumarin derivative into a TiO2 nanocrystalline film investigated by visible-to-IR ultrafast spectroscopy. Journal of Physical Chemistry B. ,vol. 109, pp. 16406- 16414 ,(2005) , 10.1021/JP0513263
Zhong-Sheng Wang, Nagatoshi Koumura, Yan Cui, Masabumi Takahashi, Hiroki Sekiguchi, Atsunori Mori, Toshitaka Kubo, Akihiro Furube, Kohjiro Hara, Hexylthiophene-Functionalized Carbazole Dyes for Efficient Molecular Photovoltaics: Tuning of Solar-Cell Performance by Structural Modification Chemistry of Materials. ,vol. 20, pp. 3993- 4003 ,(2008) , 10.1021/CM8003276
Zhong-Sheng Wang, Kazuhiro Sayama, Hideki Sugihara, Efficient Eosin Y Dye-Sensitized Solar Cell Containing Br-/Br3- Electrolyte Journal of Physical Chemistry B. ,vol. 109, pp. 22449- 22455 ,(2005) , 10.1021/JP053260H
Motonari Adachi, Masaru Sakamoto, Jinting Jiu, Yukio Ogata, Seiji Isoda, Determination of Parameters of Electron Transport in Dye-Sensitized Solar Cells Using Electrochemical Impedance Spectroscopy The Journal of Physical Chemistry B. ,vol. 110, pp. 13872- 13880 ,(2006) , 10.1021/JP061693U
Qing Wang, Jacques-E. Moser, Michael Grätzel, Electrochemical Impedance Spectroscopic Analysis of Dye-Sensitized Solar Cells Journal of Physical Chemistry B. ,vol. 109, pp. 14945- 14953 ,(2005) , 10.1021/JP052768H
Anders. Hagfeldt, Michael. Graetzel, Light-Induced Redox Reactions in Nanocrystalline Systems Chemical Reviews. ,vol. 95, pp. 49- 68 ,(1995) , 10.1021/CR00033A003