Glycosides of Calotropis procera R.Br. Glycosides and aglycones. 320

作者: F. Brüschweiler , W. Stöcklin , K. Stöckel , T. Reichstein

DOI: 10.1002/HLCA.19690520731

关键词:

摘要: From the latex of Calotropis procera, HESSEet al. [2] had isolated free calotropagenin (8) and six its glycosides. We now obtained three additional compounds: uzarigenin (4), syriogenin [10] (a 3 β, 14α, x-trihydroxy-card-(20:22)-enolide) proceroside. The latter is a new glycoside containing sugar moiety identical or stereoisomeric with those present in gomphoside, calactin calotropin. Its aglycone, not yet known form, contains one (probably secondary) hydroxyl group more than most probably 2α, 3β, 14β, x-tetrahydroxy-card-(20:22)-enolide.

参考文章(58)
I. E. Bush, D. A. H. Taylor, The paper-chromatographic examination of the cardiac aglycones of Strophanthus seeds Biochemical Journal. ,vol. 52, pp. 643- 648 ,(1952) , 10.1042/BJ0520643
R. Brandt, W. Stöcklin, T. Reichstein, Alloglaucotoxigenin, Strukturbestimmung Glykoside und Aglykone, 280. Mitteilung Helvetica Chimica Acta. ,vol. 49, pp. 1662- 1680 ,(1966) , 10.1002/HLCA.19660490527
Gerhard Hesse, Friedrich Exner, Hasso Hertel, Iso-Methylreduktinsäure Und Methylreduktinsäure Justus Liebigs Annalen der Chemie. ,vol. 609, pp. 57- 69 ,(1957) , 10.1002/JLAC.19576090106
T. Reichstein, J. von Euw, J. A. Parsons, M. Rothschild, Heart Poisons in the Monarch Butterfly Science. ,vol. 161, pp. 861- 866 ,(1968) , 10.1126/SCIENCE.161.3844.861
Gerhard Hesse, Konrad Mix, Ungewöhnlich verlaufende Oxydationen mit Perjodsäure, I Chemische Berichte. ,vol. 92, pp. 2427- 2434 ,(1959) , 10.1002/CBER.19590921007
H. T. Gordon, Wayne. Thornburg, L. N. Werum, Rapid Paper Chromatography or Carbohydrates and Related Compounds Analytical Chemistry. ,vol. 28, pp. 849- 855 ,(1956) , 10.1021/AC60113A020
G. Spiteller, Strukturuntersuchung organischer Verbindungen mit Hilfe der Massenspektrometrie Fresenius Journal of Analytical Chemistry. ,vol. 197, pp. 1- 15 ,(1963) , 10.1007/BF00468721