Highly conductive PEDOT:PSS nanofibrils induced by solution-processed crystallization.
作者： Nara Kim , Seyoung Kee , Seoung Ho Lee , Byoung Hoon Lee , Yung Ho Kahng
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摘要: Abstract Crystalline poly (3, 4-ethylenedioxythiophene) poly (styrenesulfonate)(PEDOT: PSS) nanofibrils with an electrical conductivity of 4380 S cm-1 are formed via a solution process using H 2 SO 4. The concentrated H 2 SO 4 treatment induces a significant structural rearrangement of the PEDOT: PSS via a charge-separated transition mechanism, resulting in highly ordered and densely packed PEDOT: PSS nanofibrils. The PEDOT: PSS electrode shows a sheet resistance of 46 Ω sq-1 with 90% optical transmittance.
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researchgate.net 参考文章(24)
Manrico V Fabretto, Drew R Evans, Michael Mueller, Kamil Zuber, Pejman Hojati-Talemi, Rob D Short, Gordon G Wallace, Peter J Murphy, None, Polymeric material with metal-like conductivity for next generation organic electronic devices Chemistry of Materials. ,vol. 24, pp. 3998- 4003 ,(2012) , 10.1021/CM302899V
L. Groenendaal, F. Jonas, D. Freitag, H. Pielartzik, J. R. Reynolds, Poly(3,4‐ethylenedioxythiophene) and Its Derivatives: Past, Present, and Future Advanced Materials. ,vol. 12, pp. 481- 494 ,(2000) , 10.1002/(SICI)1521-4095(200004)12:7<481::AID-ADMA481>3.0.CO;2-C
Klaus Ellmer, Past achievements and future challenges in the development of optically transparent electrodes Nature Photonics. ,vol. 6, pp. 809- 817 ,(2012) , 10.1038/NPHOTON.2012.282
R. J. Gillespie, E. A. Robinson, THE RAMAN SPECTRA OF SULPHURIC, DEUTEROSULPHURIC, FLUOROSULPHURIC, CHLOROSULPHURIC, AND METHANESULPHONIC ACIDS AND THEIR ANIONS Canadian Journal of Chemistry. ,vol. 40, pp. 644- 657 ,(1962) , 10.1139/V62-100
Yijie Xia, Kuan Sun, Jianyong Ouyang, Solution‐Processed Metallic Conducting Polymer Films as Transparent Electrode of Optoelectronic Devices Advanced Materials. ,vol. 24, pp. 2436- 2440 ,(2012) , 10.1002/ADMA.201104795
Stephen R. Forrest, The path to ubiquitous and low-cost organic electronic appliances on plastic Nature. ,vol. 428, pp. 911- 918 ,(2004) , 10.1038/NATURE02498
Olle Inganäs, Organic photovoltaics: Avoiding indium Nature Photonics. ,vol. 5, pp. 201- 202 ,(2011) , 10.1038/NPHOTON.2011.46
Brian G. Lewis, David C. Paine, Applications and Processing of Transparent Conducting Oxides Mrs Bulletin. ,vol. 25, pp. 22- 27 ,(2000) , 10.1557/MRS2000.147
Yijie Xia, Jianyong Ouyang, Salt-Induced Charge Screening and Significant Conductivity Enhancement of Conducting Poly(3,4-ethylenedioxythiophene):Poly(styrenesulfonate) Macromolecules. ,vol. 42, pp. 4141- 4147 ,(2009) , 10.1021/MA900327D
Leif A.A Pettersson, Soumyadeb Ghosh, Olle Inganäs, Optical anisotropy in thin films of poly(3,4-ethylenedioxythiophene)–poly(4-styrenesulfonate) Organic Electronics. ,vol. 3, pp. 143- 148 ,(2002) , 10.1016/S1566-1199(02)00051-4