Effects of nanoscale SiO2 on the thermal and transport properties of solvent-free, poly(ethylene oxide) (PEO)-based polymer electrolytes
作者： Claudio Capiglia , Piercarlo Mustarelli , Eliana Quartarone , Corrado Tomasi , Aldo Magistris
DOI: 10.1016/S0167-2738(98)00457-3
关键词:
摘要: Solvent-free, composite electrolytes based on poly(ethylene oxide) (PEO) have been prepared by using LiClO4 and LiN(CF3SO2)2 as the doping salts, nanoscale SiO2 filler. The samples characterized for what concerns their thermal transport properties. addition of filler determines an increase conductivity more than one order-of-magnitude, depending concentration. maximum value 1.4×10−4 ohm−1 cm−1 is obtained sample PEO8–LiN(CF3SO2)2–5 wt% SiO2. Effects silica history level also ascertained. cation number, t+, changes from ~0.1 to ~0.2 when 10 added.
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