A Study on the Synthesis and Properties of Polyurethane/Clay Nanocomposites
作者： Lei Song , Yuan Hu , Baoguang Li , Shaofeng Wang , Weicheng Fan
关键词:
摘要: Polyurethane/organophilic montmorillonite (PU/OMT) nanocomposites based on polyether, organophilic montmorillonite, phenylmethane diisocyante, diglycol, and glycerine were synthesized characterized by x-ray diffraction (XRD). Delaminated or intercalated structures in polyurethane/OMT with different OMT content found. The mechanical, thermal, inflammability properties of PU/OMT investigated through tensile, thermogravimetry, differential scanning calorimetry, cone calorimetry experiments. It is shown that have enhanced tensile strength, improved thermal stability, flame retardant relative to bulk polyurethane. strength 4.7 wt% was double compared PU. increased increasing content.
sci-hub.se 参考文章(11)
T-K Chen, Y-I Tien, K-H Wei, Synthesis and characterization of novel segmented polyurethane/clay nanocomposites Polymer. ,vol. 41, pp. 1345- 1353 ,(2000) , 10.1016/S0032-3861(99)00280-3
Tie Lan, Padmananda D. Kaviratna, Thomas J. Pinnavaia, On the Nature of Polyimide-Clay Hybrid Composites Chemistry of Materials. ,vol. 6, pp. 573- 575 ,(1994) , 10.1021/CM00041A002
A. Akelah, P. Kelly, S. Qutubuddin, A. Moet, Synthesis and characterization of epoxyphilic' montmorillonites Clay Minerals. ,vol. 29, pp. 169- 178 ,(1994) , 10.1180/CLAYMIN.1994.029.2.03
Dong Choo Lee, Lee Wook Jang, Preparation and Characterization of PMMA-Clay Hybrid Composite by Emulsion Polymerization Journal of Applied Polymer Science. ,vol. 61, pp. 1117- 1122 ,(1996) , 10.1002/(SICI)1097-4628(19960815)61:7<1117::AID-APP7>3.0.CO;2-P
Kazuhisa Yano, Arimitsu Usuki, Akane Okada, Toshio Kurauchi, Osami Kamigaito, Synthesis and properties of polyimide–clay hybrid Journal of Polymer Science Part A. ,vol. 31, pp. 2493- 2498 ,(1993) , 10.1002/POLA.1993.080311009
Emmanuel P. Giannelis, Polymer Layered Silicate Nanocomposites Advanced Materials. ,vol. 8, pp. 29- 35 ,(1996) , 10.1002/ADMA.19960080104
Piotr Penczek, Kurt C. Frisch, Barbara Szczepaniak, Ewa Rudnik, Synthesis and properties of liquid crystalline polyurethanes Journal of Polymer Science Part A. ,vol. 31, pp. 1211- 1220 ,(1993) , 10.1002/POLA.1993.080310517
Arimitsu Usuki, Toshio Kurauchi, Megumi Fujimoto, Yoshitsugu Kojima, Osami Kamigaito, Norio Sato, Kenzo Fukumori, Tadashi Mizutani, Yoshiaki Fukushima, Composite material containing a layered silicate ,(1988)
P LeBaron, Polymer-layered silicate nanocomposites: an overview Applied Clay Science. ,vol. 15, pp. 11- 29 ,(1999) , 10.1016/S0169-1317(99)00017-4
Yoshitsugu Kojima, Arimitsu Usuki, Masaya Kawasumi, Akane Okada, Toshio Kurauchi, Osami Kamigaito, One‐pot synthesis of nylon 6–clay hybrid Journal of Polymer Science Part A. ,vol. 31, pp. 1755- 1758 ,(1993) , 10.1002/POLA.1993.080310714