Recent advances in the application of Diels-Alder reactions involving o-quinodimethanes, aza-o-quinone methides and o-quinone methides in natural product total synthesis.
作者： Baochao Yang , Shuanhu Gao
DOI: 10.1039/C8CS00274F
关键词:
摘要: In recent decades, transient and highly reactive ortho-quinodimethanes (o-QDMs), ortho-quinone methides (o-QMs) aza-ortho-quinone (aza-o-QMs) have attracted much attention been extensively studied applied in organic synthesis, especially natural product total synthesis. This review summarizes advances Diels–Alder reactions involving situ-generated o-QDMs, o-QMs aza-o-QMs, highlighting the power potential of this strategy synthesis An overview methods for generating these intermediates is also available.
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