Topological and Thermodynamic Investigations of Ternary Mixtures Containing Cyclic Ethers: Excess Molar Volumes

摘要: Excess molar volumes, \(V_{123}^{\mathrm{E}}\), of 1,3-dioxolane or 1,4-dioxane (1) + aniline (2) benzene toluene (3) ternary mixtures have been determined over the entire mole fraction range at 308.15 K. \(V_{123}^{\mathrm{E}}\) data fitted to Redlich-Kister equation evaluate adjustable parameters and standard deviations. The observed analyzed in terms (i) Graph theory, (ii) Prigogine-Flory-Patterson (iii) Sanchez Lacombe theory. It has that values predicted by theory compare well with corresponding experimental values.