Cation-directed orientation of amines in ternary graphite intercalation compounds
作者： Tosapol Maluangnont , Kazuma Gotoh , Kazuya Fujiwara , Michael M. Lerner
DOI: 10.1016/J.CARBON.2010.10.052
关键词:
摘要: Abstract 1,2-Diaminopropane (1,2-DAP) provides an unusual example of organic co-intercalate where graphite intercalation compounds (GICs) show intra-gallery orientation dependant on the identity alkali metal cation intercalate (Li+, Na+, or K+). The GIC gallery heights, K(1,2-DAP)yCx = 0.697 nm and Li(1,2-DAP)yCx = 0.782 nm, indicate 1,2-DAP long axis orientations that are parallel perpendicular to graphene sheets, respectively.
elsevier.com
sci-hub.se 参考文章(6)
Toshiaki Enoki, Morinobu Endo, Masatsugu Suzuki, Graphite Intercalation Compounds and Applications ,(2003)
G. Merle, J. M. Létoffé, I. B. Rashkov, P. Claudy, Action des molecules organiques sur les composes d'insertion de metaux alcalins dans le graphite Journal of Thermal Analysis and Calorimetry. ,vol. 13, pp. 293- 305 ,(1978) , 10.1007/BF01912302
C. Schmidt, M. E. Rosen, D. F. Caplan, A. Pines, M. F. Quinton, Orientation and Motion of Tetrahydrofuran in Graphite Intercalation Compounds: Proton NMR Studies of Cs(THF)1.3C24 and K(THF)2.5C24 The Journal of Physical Chemistry. ,vol. 99, pp. 10565- 10572 ,(1995) , 10.1021/J100026A020
F. Beguin, B. Gonzalez, J. Conard, H. Estrade-Szwarckopf, D. Guerard, Structure and transitions in coordinated lithium graphite intercalation compounds Synthetic Metals. ,vol. 12, pp. 187- 193 ,(1985) , 10.1016/0379-6779(85)90108-0
Julián Morales, Jesús Santos, José R. Ramos Barrado, Juán P. Espinós, Agustín R. González-Elipe, Synthesis and characterization of diamine intercalation compounds of SnS2 single crystals Journal of Solid State Chemistry. ,vol. 150, pp. 391- 398 ,(2000) , 10.1006/JSSC.1999.8612
R. Moreh, H. Pinto, Y. Finkelstein, F. Beguin, Tilt of N2 molecules physintercalated into C24K and C24Rb Journal of Physics and Chemistry of Solids. ,vol. 57, pp. 909- 913 ,(1996) , 10.1016/0022-3697(95)00372-X