catena-Poly[[diaqua(isonicotinato-κ2O,O′)dysprosium(III)]-di-μ-isonicotinato-κ4O:O′]

作者: Guo-Ming Wang , Bo Xu , Hui-Luan Liu , Qing-Hua Zheng

DOI: 10.1107/S1600536806041559

关键词:

摘要: In the title compound, [Er(IN)3(H2O)2]n, where IN is isonicotinate anion, C6H4NO2−, asymmetric unit contains one half-mol­ecule. The ErIII atom lies on a crystallographic twofold axis and coordinated by four two carboxyl­ate O atoms from bridging chelating groups, respectively, water mol­ecules, yielding an eight-coordinate square-anti­prismatic geometry. crystal structure, polymer features infinite doubly carboxyl­ate-bridged chain-like structure with group each metal centre. Adjacent chains are, in turn, connected to other through inter­molecular O—H⋯O O—H⋯N hydrogen bonds, forming three-dimensional network.

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