Synthesis of few-walled carbon nanotube–Rh nanoparticles by arc discharge: Effect of selective oxidation
作者： Yanfeng Zhang
DOI: 10.1016/J.MATCHAR.2012.03.013
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摘要: Abstract Highly crystalline rhodium (Rh) nanoparticles supported on carbon nanotubes were prepared by selective oxidation method. Carbon and FeRh simultaneously generated in hydrogen arc plasma. The as-grown nanomaterials can be purified heat treatment open air soaking HCl. X-ray diffraction selected area electron results reveal that have a typical chemical CsCl-type structure which transformed into face-centered cubic thermal annealing the purification process. process is toward removal of amorphous coating nanoparticles, transforms Fe to Fe2O3. Fe2O3 easily dissolved hydrochloric acid, leaving nanotubes–Rh nanoparticles. Rh with diameters 2–60 nm are deposited uniformly surface nanotube bundles. This simple chemistry offers new for synthesizing controlling content nanotube–FeRh
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Leimei Sheng, Lei Shi, Kang An, Liming Yu, Yoshinori Ando, Xinluo Zhao, Effective and efficient purification of single-wall carbon nanotubes based on hydrogen treatment Chemical Physics Letters. ,vol. 502, pp. 101- 106 ,(2011) , 10.1016/J.CPLETT.2010.12.034
Hnin Yu Yu Ko, Takao Suzuki, Nguyen N. Phuoc, Jiangwei Cao, Fabrication and characterization of FeRh nanoparticles Journal of Applied Physics. ,vol. 103, ,(2008) , 10.1063/1.2832440
Hitoshi Kusama, Kiyomi Okabe, Kazuhiro Sayama, Hironori Arakawa, Ethanol synthesis by catalytic hydrogenation of CO2 over RhFeSiO2 catalysts Energy. ,vol. 22, pp. 343- 348 ,(1997) , 10.1016/S0360-5442(96)00095-3
D. Reznik, C. H. Olk, D. A. Neumann, J. R. D. Copley, X-ray powder diffraction from carbon nanotubes and nanoparticles Physical Review B. ,vol. 52, pp. 116- 124 ,(1995) , 10.1103/PHYSREVB.52.116
Jia Gao, Xunhua Mo, James G. Goodwin Jr., La, V, and Fe promotion of Rh/SiO2 for CO hydrogenation: Detailed analysis of kinetics and mechanism Journal of Catalysis. ,vol. 268, pp. 142- 149 ,(2009) , 10.1016/J.JCAT.2009.09.012
Makarand R. Gogate, Robert J. Davis, Comparative study of CO and CO2 hydrogenation over supported Rh–Fe catalysts Catalysis Communications. ,vol. 11, pp. 901- 906 ,(2010) , 10.1016/J.CATCOM.2010.03.020
Philippe Serp, Massimiliano Corrias, Philippe Kalck, Carbon nanotubes and nanofibers in catalysis Applied Catalysis A-general. ,vol. 253, pp. 337- 358 ,(2003) , 10.1016/S0926-860X(03)00549-0
Hisanori Tanaka, Rie Kaino, Yoshinao Nakagawa, Keiichi Tomishige, Comparative study of Rh/MgO modified with Fe, Co or Ni for the catalytic partial oxidation of methane at short contact time. Part II: Catalytic performance and bed temperature profile Applied Catalysis A-general. ,vol. 378, pp. 187- 194 ,(2010) , 10.1016/J.APCATA.2010.02.018
A. Thess, R. Lee, P. Nikolaev, H. Dai, P. Petit, J. Robert, C. Xu, Y. H. Lee, S. G. Kim, A. G. Rinzler, D. T. Colbert, G. E. Scuseria, D. Tomanek, J. E. Fischer, R. E. Smalley, Crystalline Ropes of Metallic Carbon Nanotubes Science. ,vol. 273, pp. 483- 487 ,(1996) , 10.1126/SCIENCE.273.5274.483
Guiquan Guo, Feng Qin, Dong Yang, Changchun Wang, Hualong Xu, Shu Yang, Synthesis of Platinum Nanoparticles Supported on Poly(acrylic acid) Grafted MWNTs and Their Hydrogenation of Citral Chemistry of Materials. ,vol. 20, pp. 2291- 2297 ,(2008) , 10.1021/CM703225P