Proton Relaxation Times in Paramagnetic Solutions. Effects of Electron Spin Relaxation
作者： N. Bloembergen , L. O. Morgan
DOI: 10.1063/1.1731684
关键词:
摘要: The proton relaxation time in solutions of paramagnetic ions depends, among other factors, on the electron spins, τs. It is shown that latter, for iron group, determined mostly by distortion hydrated complex collisions with water molecules. theory provides a quantitative explanation decrease T2 Mn++ (and other) very high magnetic fields. experimentally observed field and temperature dependence times, T1 T2, group compared features which depend τs are stressed.
scitation.org
harvard.edu
aip.org
sci-hub.se 参考文章(24)
L. C. Hebel, C. P. Slichter, Nuclear spin relaxation in normal and superconducting aluminum Physical Review. ,vol. 113, pp. 1504- 1519 ,(1959) , 10.1103/PHYSREV.113.1504
M. Weger, W. Low, Paramagnetic Resonance Spectrum of Gadolinium in Hydrated Lanthanum Trichloride Physical Review. ,vol. 111, pp. 1526- 1528 ,(1958) , 10.1103/PHYSREV.111.1526
Harden M. McConnell, Effect of Anisotropic Hyperfine Interactions on Paramagnetic Relaxation in Liquids The Journal of Chemical Physics. ,vol. 25, pp. 709- 711 ,(1956) , 10.1063/1.1743033
I. Solomon, Relaxation Processes in a System of Two Spins Physical Review. ,vol. 99, pp. 559- 565 ,(1955) , 10.1103/PHYSREV.99.559
J. H. Van Vleck, Paramagnetic Relaxation Times for Titanium and Chrome Alum Physical Review. ,vol. 57, pp. 426- 447 ,(1940) , 10.1103/PHYSREV.57.426
R. Hausser, G. Laukien, Messung und Deutung der Temperaturabhängigkeit der kernmagnetischen Protonenrelaxation in wäßrigen Lösungen von Ionen der I. Gruppe der Übergangselemente European Physical Journal. ,vol. 153, pp. 394- 411 ,(1959) , 10.1007/BF01337607
R. N. Rogers, G. E. Pake, Paramagnetic Relaxation in Solutions of VO++ The Journal of Chemical Physics. ,vol. 33, pp. 1107- 1111 ,(1960) , 10.1063/1.1731342
John P. Hunt, Henry Taube, The Exchange of Water between Aqueous Chromic Ion and Solvent The Journal of Chemical Physics. ,vol. 18, pp. 757- 758 ,(1950) , 10.1063/1.1747745
A. Abragam, R. V. Pound, INFLUENCE OF ELECTRIC AND MAGNETIC FIELDS ON ANGULAR CORRELATIONS Physical Review. ,vol. 92, pp. 943- 962 ,(1953) , 10.1103/PHYSREV.92.943
M. E. Rose, Elementary Theory of Angular Momentum ,(1957)