Electrical conductivity of polystyrene/poly(n-alkyl methacrylate)s / carbon nanotube ternary composite casting films

作者: Huagen Xu , Dirk W. Schubert

DOI: 10.1007/S10965-020-02141-1

关键词:

摘要: In this work, poly(n-alkyl methacrylate)s (P-alkyl-MA)/Polystyrene (PS)/Carbon nanotube (CNT) composite films with different CNT concentration and polymer blend ratio were prepared utilizing solution casting method. Light microscope scanning electron used to investigate the location in blends morphology of ternary films. The electrical conductivity investigated, all percolation thresholds (ϕc) PS/P-alkyl-MA/CNT determined experimental data are fitted McLachlan’s equation. fitting indicate both PS/PMMA/CNT PS/PEMA/CNT show an obviously double effect at 50/50. Compared pure PMMA PEMA, ϕc when PS /PMMA =50/50 PS/PEMA decreased by 69.0% 73.1%, respectively. A contour plot based on presented as a function ratio. With content increasing P-alkyl-MA/PS blends, PS/PMMA/ PS/PEMA/ shows similar tendency. certain was explain changing

参考文章(40)
Zdeněk Starý, Johannes Krückel, Constantin Weck, Dirk W. Schubert, Rheology and conductivity of carbon fibre composites with defined fibre lengths Composites Science and Technology. ,vol. 85, pp. 58- 64 ,(2013) , 10.1016/J.COMPSCITECH.2013.06.006
Anne-Christine Baudouin, Jacques Devaux, Christian Bailly, Localization of carbon nanotubes at the interface in blends of polyamide and ethylene-acrylate copolymer Polymer. ,vol. 51, pp. 1341- 1354 ,(2010) , 10.1016/J.POLYMER.2010.01.050
Hua Deng, Lin Lin, Mizhi Ji, Shuangmei Zhang, Mingbo Yang, Qiang Fu, Progress on the morphological control of conductive network in conductive polymer composites and the use as electroactive multifunctional materials Progress in Polymer Science. ,vol. 39, pp. 627- 655 ,(2014) , 10.1016/J.PROGPOLYMSCI.2013.07.007
F. Gubbels, R. Jerome, Ph. Teyssie, E. Vanlathem, R. Deltour, A. Calderone, V. Parente, J. L. Bredas, Selective localization of carbon black in immiscible polymer blends: A useful tool to design electrical conductive composites Macromolecules. ,vol. 27, pp. 1972- 1974 ,(1994) , 10.1021/MA00085A049
Masao Sumita, Kazuya Sakata, Shigeo Asai, Keizo Miyasaka, Hideaki Nakagawa, Dispersion of fillers and the electrical conductivity of polymer blends filled with carbon black Polymer Bulletin. ,vol. 25, pp. 265- 271 ,(1991) , 10.1007/BF00310802