Direct Observation of Ag Filamentary Paths in Organic Resistive Memory Devices

作者: Byungjin Cho , Jin-Mun Yun , Sunghoon Song , Yongsung Ji , Dong-Yu Kim

DOI: 10.1002/ADFM.201101210

关键词:

摘要: We demonstrate bipolar switching of organic resistive memory devices consisting Ag/polymer/heavily-doped p-type poly Si junctions in an 8 × cross-bar array structure. The bistable mechanism appears to be related the formation and rupture highly conductive paths, as shown by a direct observation Ag metallic bridges using transmission electron microscopy energy-dispersive X-ray spectroscopy. Current images high- low-conducting states acquired conducting atomic force also support this filamentary mechanism. can described electrochemical redox reaction model Ag. Our results may applied other kinds materials presenting similar properties, contributing optimization device scaling or performance improvement.

参考文章(39)
W. Hwang, K. C. Kao, On the theory of filamentary double injection and electroluminescence in molecular crystals Journal of Chemical Physics. ,vol. 60, pp. 3845- 3855 ,(1974) , 10.1063/1.1680828
Tae-Wook Kim, Seung-Hwan Oh, Joonmyoung Lee, Hyejung Choi, Gunuk Wang, Jubong Park, Dong-Yu Kim, Hyunsang Hwang, Takhee Lee, None, Effect of metal ions on the switching performance of polyfluorene-based organic non-volatile memory devices Organic Electronics. ,vol. 11, pp. 109- 114 ,(2010) , 10.1016/J.ORGEL.2009.10.006
Byungjin Cho, Tae-Wook Kim, Sunghoon Song, Yongsung Ji, Minseok Jo, Hyunsang Hwang, Gun-Young Jung, Takhee Lee, Rewritable Switching of One Diode–One Resistor Nonvolatile Organic Memory Devices Advanced Materials. ,vol. 22, pp. 1228- 1232 ,(2010) , 10.1002/ADMA.200903203
Xiao-Dong Zhuang, Yu Chen, Gang Liu, Bin Zhang, Koon-Gee Neoh, En-Tang Kang, Chun-Xiang Zhu, Yong-Xi Li, Li-Juan Niu, Preparation and Memory Performance of a Nanoaggregated Dispersed Red 1‐Functionalized Poly (N‐vinylcarbazole) Film via Solution‐Phase Self‐Assembly Advanced Functional Materials. ,vol. 20, pp. 2916- 2922 ,(2010) , 10.1002/ADFM.201000258
Sunghoon Song, Byungjin Cho, Tae-Wook Kim, Yongsung Ji, Minseok Jo, Gunuk Wang, Minhyeok Choe, Yung Ho Kahng, Hyunsang Hwang, Takhee Lee, Three-Dimensional Integration of Organic Resistive Memory Devices Advanced Materials. ,vol. 22, pp. 5048- 5052 ,(2010) , 10.1002/ADMA.201002575
Biswanath Mukherjee, Amlan J. Pal, Tuning of electrical bistability in organic devices through electrochemical potential of metal contacts Organic Electronics. ,vol. 7, pp. 249- 255 ,(2006) , 10.1016/J.ORGEL.2006.03.004
Tae-Wook Kim, Seung-Hwan Oh, Hyejung Choi, Gunuk Wang, Hyunsang Hwang, Dong-Yu Kim, Takhee Lee, Reversible switching characteristics of polyfluorene-derivative single layer film for nonvolatile memory devices Applied Physics Letters. ,vol. 92, pp. 253308- ,(2008) , 10.1063/1.2952825
Byungjin Cho, Sunghoon Song, Yongsung Ji, Takhee Lee, Electrical characterization of organic resistive memory with interfacial oxide layers formed by O2 plasma treatment Applied Physics Letters. ,vol. 97, pp. 063305- ,(2010) , 10.1063/1.3478840
Won-Jae Joo, Tae-Lim Choi, Jaeho Lee, Sang Kyun Lee, Myung-Sup Jung, Nakjoong Kim, Jong Min Kim, Metal Filament Growth in Electrically Conductive Polymers for Nonvolatile Memory Application Journal of Physical Chemistry B. ,vol. 110, pp. 23812- 23816 ,(2006) , 10.1021/JP0649899