Applications of calorimetry to nonelectrolyte solutions
作者： J. Bevan Ott , Jadwiga T. Sipowska
DOI: 10.1021/JE960105A
关键词:
摘要: This paper describes the application of calorimetry to measurement excess molar enthalpies for binary mixtures nonelectrolytes. Batch, displacement, and flow calorimeters are described, using as examples batch calorimeter McGlashan;, displacement Van Ness Marsh Stokes, Christensen, Wormald, Picker. Applications described measure {(nonpolar + nonpolar), (polar polar)} mixtures. Excess liquid containing charge-transfer complexes hydrogen bonds used help in understanding nature molecular interactions these systems. involving measurements on liquid, gas, supercritical fluid mixtures, including near-critical region, also described. The use calorimetric determine {(liquid liquid) (vapor liquid)} phase equilibria is discussed. Finally, equations repre...
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