Electrochemical oxidation of organosilicon compounds
作者： Jun-ichi Yoshida , Toshiki Murata , Sachihiko Isoe
DOI: 10.1016/0022-328X(88)80104-9
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摘要: Abstract Substitution of a silyl group for hydrogen at the α-position ethers caused significant decrease in their oxidation potentials. This effect is attributed to an interaction carbonsilicon σ-bond with lone pair oxygen atom. The preparative anodic α-silylethers proceeded smoothly methanol and bond was selectively cleaved give corresponding acetals.
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